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692492

Sigma-Aldrich

(R)-RuCl[(p-cymene)(BINAP)]Cl

Synonym(s):

Chloro[(R)-(+)-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl](p-cymene)ruthenium(II) chloride

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About This Item

Linear Formula:
[C54H46ClP2Ru]+Cl-
CAS Number:
145926-28-9
Molecular Weight:
928.87
MDL number:
MFCD00134456
UNSPSC Code:
12352005
PubChem Substance ID:
329761502
NACRES:
NA.22

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form

powder

Quality Level

100

functional group

phosphine

storage temp.

2-8°C

SMILES string

[Cl-].Cl[Ru+].C[C]1[CH][CH][C]([CH][CH]1)C(C)C.c2ccc(cc2)P(c3ccccc3)c4ccc5ccccc5c4-c6c(ccc7ccccc67)P(c8ccccc8)c9ccccc9

InChI

1S/C44H32P2.C10H14.2ClH.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-8(2)10-6-4-9(3)5-7-10;;;/h1-32H;4-8H,1-3H3;2*1H;/q;;;;+2/p-2

InChI key

WNHLGYRPKARUHY-UHFFFAOYSA-L

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This Item
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(R)-RuCl[(p-cymene)(BINAP)]Cl

Sigma-Aldrich

692492

(R)-RuCl[(p-cymene)(BINAP)]Cl

(S)-RuCl[(p-cymene(BINAP)]Cl

Sigma-Aldrich

692972

(S)-RuCl[(p-cymene(BINAP)]Cl

(S)-RuCl[(p-cymene)(T-BINAP)]Cl

Sigma-Aldrich

692964

(S)-RuCl[(p-cymene)(T-BINAP)]Cl

(R)−RuCl[(p−cymene)(SEGPHOS®)]Cl

Sigma-Aldrich

692522

(R)−RuCl[(p−cymene)(SEGPHOS®)]Cl

functional group

phosphine

functional group

phosphine

functional group

-

functional group

-

form

powder

form

powder

form

powder

form

powder

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

2-8°C

Application

Takasago Ligands and Complexes for Asymmetric Reactions

Legal Information

Sold in collaboration with Takasago for research purposes only.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

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Certificates of Analysis (COA)

Lot/Batch Number
MKCS0544
MKCK3103
MKBV1437V
MKAA4640
06926HJ

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Articles

Takasago Ligands

Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago

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