Skip to Content
MilliporeSigma

692786

Sigma-Aldrich

(S,S)-DACH-naphthyl Trost Ligand

95%

Synonym(s):

(1S,2S)-(–)-1,2-Diaminocyclohexane-N,N′-bis(2-diphenylphosphino-1-naphthoyl)

Slide 1 of 2
Sign Into View Organizational & Contract Pricing

Select a Size

250 MG
$57.78
1 G
$192.50

$57.78

List Price$72.50Save 20%
Web-Only Promotion

In StockDetails


Shipping Frequency

Select a Size

Change View
250 MG
$57.78
1 G
$192.50

About This Item

Empirical Formula (Hill Notation):
C52H44N2O2P2
CAS Number:
Molecular Weight:
790.87
MDL number:
UNSPSC Code:
12352005
PubChem Substance ID:
NACRES:
NA.22

Skip To

Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

$57.78

List Price$72.50Save 20%
Web-Only Promotion

In StockDetails


Shipping Frequency
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

Quality Level

assay

95%

form

solid

optical activity

[α]20/D -66.0°, c = 1 in methanol

mp

232-237 °C

functional group

amide
phosphine

SMILES string

O=C(N[C@H]1CCCC[C@@H]1NC(=O)c2c(ccc3ccccc23)P(c4ccccc4)c5ccccc5)c6c(ccc7ccccc67)P(c8ccccc8)c9ccccc9

InChI

1S/C52H44N2O2P2/c55-51(49-43-29-15-13-19-37(43)33-35-47(49)57(39-21-5-1-6-22-39)40-23-7-2-8-24-40)53-45-31-17-18-32-46(45)54-52(56)50-44-30-16-14-20-38(44)34-36-48(50)58(41-25-9-3-10-26-41)42-27-11-4-12-28-42/h1-16,19-30,33-36,45-46H,17-18,31-32H2,(H,53,55)(H,54,56)/t45-,46-/m0/s1

InChI key

VXFKMKXTPXVEMU-ZYBCLOSLSA-N

Compare Similar Items

View Full Comparison

Show Differences

1 of 4

This Item
692794692778692808
assay

95%

assay

95%

assay

95%

assay

95%

functional group

amide, phosphine

functional group

amide, phosphine

functional group

amide, phosphine

functional group

amide, phosphine

form

solid

form

solid

form

powder

form

solid

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

mp

232-237 °C

mp

136-142 °C

mp

224-231 °C

mp

136-142 °C

optical activity

[α]20/D -66.0°, c = 1 in methanol

optical activity

[α]20/D -134°, c = 1 in methanol

optical activity

[α]20/D +69.0°, c = 1 in methanol

optical activity

[α]20/D +131°, c = 1 in methanol

Application

Asymmetric allylic alkylation ligand.[1][2][3][4]

Legal Information

Sold in collaboration with Dr. Reddy′s Laboratories for research purposes only.

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Questions

Reviews

No rating value

Active Filters

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service