692808
(R,R)-DACH-phenyl Trost ligand
95%
Synonym(s):
(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N′-bis(2-diphenylphosphinobenzoyl)
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About This Item
Quality Level
assay
95%
form
solid
optical activity
[α]20/D +131°, c = 1 in methanol
mp
136-142 °C
functional group
amide
phosphine
SMILES string
O=C(N[C@@H]1CCCC[C@H]1NC(=O)c2ccccc2P(c3ccccc3)c4ccccc4)c5ccccc5P(c6ccccc6)c7ccccc7
InChI
1S/C44H40N2O2P2/c47-43(37-27-13-17-31-41(37)49(33-19-5-1-6-20-33)34-21-7-2-8-22-34)45-39-29-15-16-30-40(39)46-44(48)38-28-14-18-32-42(38)50(35-23-9-3-10-24-35)36-25-11-4-12-26-36/h1-14,17-28,31-32,39-40H,15-16,29-30H2,(H,45,47)(H,46,48)/t39-,40-/m1/s1
InChI key
AXMSEDAJMGFTLR-XRSDMRJBSA-N
Related Categories
1 of 4
This Item | 692794 | 692778 | 692786 |
|---|---|---|---|
| assay 95% | assay 95% | assay 95% | assay 95% |
| form solid | form solid | form powder | form solid |
| functional group amide, phosphine | functional group amide, phosphine | functional group amide, phosphine | functional group amide, phosphine |
| optical activity [α]20/D +131°, c = 1 in methanol | optical activity [α]20/D -134°, c = 1 in methanol | optical activity [α]20/D +69.0°, c = 1 in methanol | optical activity [α]20/D -66.0°, c = 1 in methanol |
| mp 136-142 °C | mp 136-142 °C | mp 224-231 °C | mp 232-237 °C |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
Application
Legal Information
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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