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697257

Copper(I) cyanide di(lithium chloride) complex solution

in anhydrous tetrahydrofuran, liquid

Synonym(s):

Copper(I) cyanide di(lithium chloride)

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Size/SKUAvailabilityPrice
50 mL

Available to ship TODAYfromMILWAUKEE

$236.00
$177.00

About This Item

Linear Formula:
CuCN · 2LiCl
Molecular Weight:
174.35
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

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Product Name

Copper(I) cyanide di(lithium chloride) complex solution, in anhydrous tetrahydrofuran

form

liquid

Quality Segment

reaction suitability

core: copper, reagent type: catalyst

concentration

in anhydrous tetrahydrofuran

density

0.999 g/mL at 25 °C

SMILES string

[Li]Cl.[Li]Cl.[Cu]C#N

InChI

1S/CN.2ClH.Cu.2Li/c1-2;;;;;/h;2*1H;;;/q;;;;2*+1/p-2

InChI key

QGXKBLXNBYNHBV-UHFFFAOYSA-L

Application

Copper(I) cyanide di(lithium chloride) complex can be used for the synthesis of organocopper(I) reagents by transmetalation with organozinc[1] and Grignard reagents. It is also a useful precursor to prepare organocuprate(I) reagents.

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718114703559696307
description

in anhydrous tetrahydrofuran

description

0.5 M in THF, density: 0.956 g/mL at 25 °C

description

0.6 M in THF

description

-

reaction suitability

core: copper, reagent type: catalyst

reaction suitability

core: manganese, reagent type: catalyst

reaction suitability

-

reaction suitability

core: copper, reagent type: catalyst

form

liquid

form

liquid

form

liquid

form

powder

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

density

0.999 g/mL at 25 °C

density

0.956 g/mL at 25 °C

density

1.05 g/mL at 25 °C

density

-

concentration

in anhydrous tetrahydrofuran

concentration

0.5 M in THF

concentration

0.6 M in THF, 16 % (w/w)

concentration

-


signalword

Danger

target_organs

Central nervous system, Respiratory system

supp_hazards

Storage Class

3 - Flammable liquids

flash_point_f

1.4 °F - closed cup - Solvent

flash_point_c

-17 °C - closed cup - Solvent

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3



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Questions

1–3 of 3 Questions  
  1. what is the concentration of the solution?

    1 answer
    1. The Copper (Cu) concentration of this solution may range from 0.95M - 1.10M. The Lithium (Li) concentration is not assigned a specification and is reported on an ‘as is’ basis. These values are lot-specific and reported in the Certificate of Analysis. Please see the link below to access a sample or lot-specific Certificate:

      https://www.sigmaaldrich.com/product/aldrich/697257#product-documentation

      Helpful?

  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  3. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

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