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697745

Sigma-Aldrich

Cobalt

Carbon coated magnetic, nanopowder, <50 nm particle size (TEM), ≥99%

Synonym(s):
Cobalt element, Cobalt-59
Empirical Formula (Hill Notation):
Co
CAS Number:
Molecular Weight:
58.93
MDL number:
PubChem Substance ID:
NACRES:
NA.23

Quality Level

material

carbon

assay

≥99%

form

nanopowder

composition

Carbon content, <8 wt. %

magnetization

>150 emu/g, Mass saturation

resistivity

6.24 μΩ-cm, 20°C

particle size

<50 nm (TEM)

surface area

BET surf. area >15 m2/g

bp

2900 °C (lit.)

density

8.9 g/mL at 25 °C (lit.)

Featured Industry

Battery Manufacturing

SMILES string

[Co]

InChI

1S/Co

InChI key

GUTLYIVDDKVIGB-UHFFFAOYSA-N

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Application

Air- and thermally-stable magnetic carbon-coated cobalt nanoparticles (nanomagnets). Carbon shell consists of approximately three graphitic layers and can be chemically functionalized using e.g. diazotization reactions.

Packaging

500 mg in glass insert

Signal Word

Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Eye Irrit. 2 - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 2

Storage Class Code

4.1B - Flammable solid hazardous materials

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US),Eyeshields,Gloves

Certificate of Analysis

Certificate of Origin

Covalently functionalized cobalt nanoparticles as a platform for magnetic separations in organic synthesis.
Robert N Grass et al.
Angewandte Chemie (International ed. in English), 46(26), 4909-4912 (2007-05-23)
Chun Ghee Tan et al.
Chemical communications (Cambridge, England), (36), 4297-4299 (2008-09-20)
To develop magnetic nanomaterials applicable to organic synthesis, the Suzuki cross-coupling method was adapted to attach a range of functional groups to carbon-coated core-shell materials via commercially-available substituted arylboronic acids.
Alexander Schätz et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 14(27), 8262-8266 (2008-07-31)
TEMPO was grafted on graphene-coated nanobeads with a magnetic cobalt core by using a general applicable "click"-chemistry protocol. The new heterogeneous CoNP-TEMPO emerged as a highly active catalyst for the chemoselective oxidation of primary and secondary alcohols using bleach as...
Luechinger, N.A.; Booth, N.; Heness, G.; Bandyopadhyay, S.; Grass, R.N.; Stark W.J.
Advanced Materials, 20, 3044-3044 (2008)
D W Su et al.
Journal of nanoscience and nanotechnology, 13(5), 3354-3359 (2013-07-19)
Highly ordered mesoporous Co3O4 nanostructures were prepared using SBA-15 silica as hard templates. The mesoporous structures were characterized by X-ray diffraction, high resolution transmission electron microscopy, and N2 adsorption/desorption isotherm analysis. The results demonstrated that the as-prepared mesoporous Co3O4 has...

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