699616
Chloro[tris(2,4-di-tert-butylphenyl)phosphite]gold
powder
Synonym(s):
[Tris(2,4-di-tert-butylphenyl)phosphite]gold chloride
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Product Name
Chloro[tris(2,4-di-tert-butylphenyl)phosphite]gold,
form
powder
reaction suitability
core: gold
reagent type: catalyst
mp
200-202 °C
SMILES string
Cl[Au].CC(C)(C)c1ccc(OP(Oc2ccc(cc2C(C)(C)C)C(C)(C)C)Oc3ccc(cc3C(C)(C)C)C(C)(C)C)c(c1)C(C)(C)C
InChI
1S/C42H63O3P.Au.ClH/c1-37(2,3)28-19-22-34(31(25-28)40(10,11)12)43-46(44-35-23-20-29(38(4,5)6)26-32(35)41(13,14)15)45-36-24-21-30(39(7,8)9)27-33(36)42(16,17)18;;/h19-27H,1-18H3;;1H/q;+1;/p-1
InChI key
GCWCLHMEYZKZRO-UHFFFAOYSA-M
Related Categories
1 of 4
This Item | 682705 | 665177 | 420727 |
|---|---|---|---|
| reaction suitability core: gold, reagent type: catalyst | reaction suitability core: gold, reagent type: catalyst | reaction suitability core: gold, reagent type: catalyst | reaction suitability core: gold, reagent type: catalyst |
| form powder | form solid | form solid | form powder |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| mp 200-202 °C | mp >300 °C | mp - | mp - |
![Chloro[tris(2,4-di-tert-butylphenyl)phosphite]gold](/deepweb/assets/sigmaaldrich/product/structures/386/294/6df0db46-002b-4599-ad6c-451c419a3fc5/640/6df0db46-002b-4599-ad6c-451c419a3fc5.png)
![Chloro[tris(para-trifluoromethylphenyl)phosphine]gold(I) 99%](/deepweb/assets/sigmaaldrich/product/structures/250/453/f96e05ee-0d9c-46a0-b0f5-818f89e15a2e/640/f96e05ee-0d9c-46a0-b0f5-818f89e15a2e.png)
Application
- Intermolecular addition of carbon nucleophiles to 1,5 and 1,6 enynes[1]
- [4C+2C] cycloadditions
- Cis-selective single-cleavagte skeletal cycloisomerization
- Diastereoselective Au-catalyzed intermolecular cyclopropanation
- Elucidating the mechanism of "endocyclic" skeletal rearrangement of 1,6-enynes
- Addition reactions
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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