Skip to Content
MilliporeSigma

700223

Sigma-Aldrich

Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III)

97%, crystals

Synonym(s):

Mn(dpm)3, Shenvi Hydrogenation Catalyst, Mn(TMHD)3, Tris(dipivaloylmethanato)manganese

Slide 1 of 2
Sign Into View Organizational & Contract Pricing

Select a Size

1 G
$55.11

$55.11

List Price$59.90Save 8%
Web-Only Promotion

In StockDetails


Request a Bulk Order

Select a Size

Change View
1 G
$55.11

About This Item

Linear Formula:
Mn(C11H19O2)3
CAS Number:
Molecular Weight:
604.74
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

Skip To

Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

$55.11

List Price$59.90Save 8%
Web-Only Promotion

In StockDetails


Request a Bulk Order
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

Product Name

Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III), 97%

assay

97%

form

crystals

reaction suitability

core: manganese
reagent type: catalyst

mp

160-170 °C

SMILES string

CC(C)(C)C(=O)\C=C(/O[Mn](O\C(=C/C(=O)C(C)(C)C)C(C)(C)C)O\C(=C/C(=O)C(C)(C)C)C(C)(C)C)C(C)(C)C

InChI

1S/3C11H20O2.Mn/c3*1-10(2,3)8(12)7-9(13)11(4,5)6;/h3*7,12H,1-6H3;/q;;;+3/p-3/b3*8-7-;

InChI key

ORZPLLPBZHORSD-LWTKGLMZSA-K

Looking for similar products? Visit Product Comparison Guide

Compare Similar Items

View Full Comparison

Show Differences

1 of 4

This Item
715301M2284328146
assay

97%

assay

-

assay

-

assay

98%

reaction suitability

core: manganese, reagent type: catalyst

reaction suitability

core: manganese, reagent type: catalyst

reaction suitability

core: manganese, reagent type: catalyst

reaction suitability

core: manganese, reagent type: catalyst

form

crystals

form

solid

form

-

form

beads

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

mp

160-170 °C

mp

>400 °C

mp

159-161 °C (dec.) (lit.)

mp

652 °C (lit.)

Application

Catalyst for:
  • Intramolecular Diels-Alder reactions
  • Single electron donor for excess electron transfer studies in DNA
  • Enantioselective synthesis
  • Borylation reactions
  • Hydrohydrazination and hydroazidation
  • Oxidative carbonylation of phenol
Notably, this non-precious metal catalyst can be used to obtain the thermodynamic hydrogenation product of olefins, selectively.

Simple, Chemoselective Hydrogenation with Thermodynamic Stereocontrol

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Questions

Reviews

No rating value

Active Filters

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service