700223
Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III)
97%, crystals
Synonym(s):
Mn(dpm)3, Shenvi Hydrogenation Catalyst, Mn(TMHD)3, Tris(dipivaloylmethanato)manganese
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Product Name
Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)manganese(III), 97%
assay
97%
form
crystals
reaction suitability
core: manganese
reagent type: catalyst
mp
160-170 °C
SMILES string
CC(C)(C)C(=O)\C=C(/O[Mn](O\C(=C/C(=O)C(C)(C)C)C(C)(C)C)O\C(=C/C(=O)C(C)(C)C)C(C)(C)C)C(C)(C)C
InChI
1S/3C11H20O2.Mn/c3*1-10(2,3)8(12)7-9(13)11(4,5)6;/h3*7,12H,1-6H3;/q;;;+3/p-3/b3*8-7-;
InChI key
ORZPLLPBZHORSD-LWTKGLMZSA-K
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This Item | 715301 | M2284 | 328146 |
|---|---|---|---|
| assay 97% | assay - | assay - | assay 98% |
| reaction suitability core: manganese, reagent type: catalyst | reaction suitability core: manganese, reagent type: catalyst | reaction suitability core: manganese, reagent type: catalyst | reaction suitability core: manganese, reagent type: catalyst |
| form crystals | form solid | form - | form beads |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| mp 160-170 °C | mp >400 °C | mp 159-161 °C (dec.) (lit.) | mp 652 °C (lit.) |
Application
- Intramolecular Diels-Alder reactions
- Single electron donor for excess electron transfer studies in DNA
- Enantioselective synthesis
- Borylation reactions
- Hydrohydrazination and hydroazidation
- Oxidative carbonylation of phenol
Simple, Chemoselective Hydrogenation with Thermodynamic Stereocontrol
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
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