701475

Dichloro[(2,6,10-dodecatriene)-1,12-diyl]ruthenium(IV)

powder

• Synonym(s): Dichloro(dodeca-2,6,10-triene-1,12-diyl)ruthenium(IV), Dichloro-2,6,10-dodecatrienylene-ruthenium, Dichloro[(1,2,3,6,7,10,11,12-η)-2,6,10-dodecatriene-1,12-diyl]-ruthenium
• Empirical Formula (Hill Notation): C₁₂H₁₈Cl₂Ru
• CAS Number: 12170-97-7
• Molecular Weight: 334.25
• UNSPSC Code: 12161600
• PubChem Substance ID: 329762293
• NACRES: NA.22
• MDL number: MFCD08459354

Properties

• Product Name: Dichloro[(2,6,10-dodecatriene)-1,12-diyl]ruthenium(IV),
• form: powder
• Quality Level: 100
• reaction suitability: core: ruthenium, reagent type: catalyst
• mp: 190 °C
• SMILES string: Cl[Ru]1(Cl)C\C=C\CCC=CCC\C=C\C1
• InChI: 1S/C12H18.2ClH.Ru/c1-3-5-7-9-11-12-10-8-6-4-2;;;/h3-6,11-12H,1-2,7-10H2;2*1H;/q;;;+2/p-2/b5-3+,6-4+,12-11-;;;
• InChI key: RSRAKQPWMXANGM-LXALEWKWSA-L

Description

Application

Catalysts used in the deprotection of N-allyl amides and lactams

Catalyst for:

• Redox isomerization/transfer hydrogenation
• Deprotection of N-allyl amides and lactams
• Isomerization of allylamines
• Isomerization of allylic alcohols into carbonyl compounds

Safety Information

• pictograms: GHS07
• signalword: Warning
• hcodes: H315,H319,H335
• pcodes: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• target_organs: Respiratory system
• Storage Class: 11 - Combustible Solids
• wgk: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: dust mask type N95 (US), Eyeshields, Gloves