703559
Lanthanum(III) chloride bis(lithium chloride) complex solution
0.6 M in THF
Synonym(s):
Lanthanum trichloride lithium chloride complex
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 25 mL | Available to ship TODAYfromMILWAUKEE | $134.00 | |
| 100 mL | Available to ship TODAYfromMILWAUKEE | $183.00 | |
| 4 x 25 mL | Available to ship TODAYfromMILWAUKEE | $456.00 |
About This Item
form
liquid
Quality Level
reaction suitability
reagent type: catalyst
core: lanthanum
reaction type: Grignard Reaction
packaging
Sure/Seal™ of
concentration
0.6 M in THF, 16 % (w/w)
density
1.05 g/mL at 25 °C
SMILES string
[Li]Cl.[Li]Cl.Cl[La](Cl)Cl
InChI
1S/5ClH.La.2Li/h5*1H;;;/q;;;;;+3;2*+1/p-5
InChI key
YSKOYVQYUJUXCN-UHFFFAOYSA-I
Application
- Mediates Grignard additions
- Reagent for metal exchange reactions
- Promoter for the addition of organometallic compounds to sterically hindered, enolizable or α,β-unsaturated ketones or imines
Legal Information
1 of 1
This Item | |||
|---|---|---|---|
| form liquid | form liquid | form - | form solid |
| concentration 0.6 M in THF, 16 % (w/w) | concentration 0.5 M in THF | concentration - | concentration - |
| density 1.05 g/mL at 25 °C | density 0.956 g/mL at 25 °C | density - | density - |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| packaging Sure/Seal™ of | packaging - | packaging - | packaging - |
| reaction suitability reagent type: catalyst | reaction suitability - | reaction suitability - | reaction suitability - |
signalword
Danger
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Sens. 1 - STOT SE 3
target_organs
Central nervous system, Respiratory system
supp_hazards
Storage Class
3 - Flammable liquids
wgk
WGK 2
flash_point_f
62.6 °F
flash_point_c
17 °C
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
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Articles
Transformative reagents enable selective conversions within molecules containing sensitive functionalities under mild reactions.
Grignard reagent's 1,2-addition to ketones is powerful but selective issues often arise from competitive alpha-deprotonation.
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 561673-50ML | 04061838128362 |
| 703559-100ML | 04061838129079 |
| 703559-25ML | 04061837768132 |
| 703559-4X25ML | 04061837768149 |