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703915
RuCl(p-cymene)[(S,S)-Ts-DPEN]
Synonym(s):
[N-[(1S,2S)-2-(Amino-κN)-1,2-diphenylethyl]-4-methylbenzenesulfonamidato-κN]chloro[(1,2,3,4,5,6-η)-1-methyl-4-(1-methylethyl)benzene]-ruthenium
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 100 mg | Estimated to ship TODAYfromMILWAUKEE | $54.10 $40.57 | |
| 500 mg | Estimated to ship TODAYfromMILWAUKEE | $149.00 |
About This Item
form
solid
Quality Level
optical activity
[α]20/D +178°, c = 0.5 in chloroform
reaction suitability
reagent type: catalyst
core: ruthenium
reaction type: Noyori Asymmetric Hydrogenation
mp
>175 °C
functional group
amine, phenyl
storage temp.
2-8°C
SMILES string
CC(C)c1ccc(C)cc1.Cc2ccc(cc2)S(=O)(=O)N([Ru]Cl)[C@H]([C@@H](N)c3ccccc3)c4ccccc4
InChI
1S/C21H21N2O2S.C10H14.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-8(2)10-6-4-9(3)5-7-10;;/h2-15,20-21H,22H2,1H3;4-8H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m0.../s1
InChI key
AZFNGPAYDKGCRB-XCPIVNJJSA-M
General description
Application
- Asymmetric transfer hydrogenation of imines and ketones
- Intramolecular asymmetric reductive amination
- Tandem hydroformylation / hydrogenation of terminal olefins
Reactant involved in studies of thermal decomposition of areneruthenium chiral amido-amine alkyl complexes
Legal Information
1 of 1
This Item | |||
|---|---|---|---|
| reaction suitability reagent type: catalyst | reaction suitability reagent type: catalyst | reaction suitability - | reaction suitability reagent type: catalyst |
| form solid | form powder | form powder or crystals | form powder |
| functional group amine, phenyl | functional group - | functional group - | functional group amine, phenyl |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| storage temp. 2-8°C | storage temp. 2-8°C | storage temp. 2-8°C | storage temp. 2-8°C |
| optical activity [α]20/D +178°, c = 0.5 in chloroform | optical activity - | optical activity - | optical activity [α]20/D −116°, c = 0.1 in chloroform |
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Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
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Articles
Hydrogenation, Asymmetric Catalysis, Binap, SEGPHOS®, Aldol reaction, Alkenylation, Arylation, Mannich reaction, Fluorination, Michael addition, Hydrosilylation, Cycloaddition, Takasago
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 703915-500MG | 04061832824048 |
| 703915-100MG | 04061833555361 |
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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