707230

Sigma-Aldrich

tert-Butyldichlorophosphine solution

1.0 M in diethyl ether

Synonym(s):
(1,1-Dimethylethyl)phosphonous dichloride solution
Empirical Formula (Hill Notation):
C4H9Cl2P
CAS Number:
Molecular Weight:
158.99
MDL number:
PubChem Substance ID:

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

Quality Level

concentration

1.0 M in diethyl ether

density

0.766 g/mL at 25 °C

functional group

phosphine

SMILES string

CC(C)(C)P(Cl)Cl

InChI

1S/C4H9Cl2P/c1-4(2,3)7(5)6/h1-3H3

InChI key

NMJASRUOIRRDSX-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Application

Reactant for:
  • The preparation of Buchwald-type secondary phosphine oxide ligands
  • Asymmetric hydrogenation

Reactant for the synthesis of:
  • Alkali metal complexes
  • P-Stereogenic compounds via kinetic deprotonation
  • Ortho-trifluoromethylphenyl-substituted phosphines

Packaging

100 mL in Sure/Seal™

Signal Word

Danger

Hazard Statements

Target Organs

Central nervous system

Supp Hazards

EUH014 - EUH019

RIDADR

UN 2924 8(3) / PGI

WGK Germany

WGK 3

Certificate of Analysis
Certificate of Origin

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service

Social Media

LinkedIn icon
Twitter icon
Facebook Icon
Instagram Icon

MilliporeSigma

Research. Development. Production.

We are a leading supplier to the global Life Science industry with solutions and services for research, biotechnology development and production, and pharmaceutical drug therapy development and production.

© 2021 Merck KGaA, Darmstadt, Germany and/or its affiliates. All Rights Reserved.

Reproduction of any materials from the site is strictly forbidden without permission.