70956

1-Butyl-3-methylimidazolium hexafluorophosphate

≥97.0% (HPLC)

• Synonym(s): BMIMPF₆
• Empirical Formula (Hill Notation): C₈H₁₅F₆N₂P
• CAS Number: 174501-64-5
• Molecular Weight: 284.18
• MDL number: MFCD03093295
• PubChem Substance ID: 57652268
• NACRES: NA.22

Properties

• Quality Level: 200
• Assay: ≥97.0% (HPLC)
• form: liquid
• refractive index: n20/D 1.411 (lit.)
• density: 1.38 g/mL at 20 °C (lit.)
• SMILES string: F[P-](F)(F)(F)(F)F.CCCCn1cc[n+](C)c1
• InChI: 1S/C8H15N2.F6P/c1-3-4-5-10-7-6-9(2)8-10;1-7(2,3,4,5)6/h6-8H,3-5H2,1-2H3;/q+1;-1
• InChI key: IXQYBUDWDLYNMA-UHFFFAOYSA-N

Description

General description

1-Butyl-3-methylimidazolium hexafluorophosphate is an imidazolium-based, hydrophobic, room temperature ionic liquid (RTIL). It can be prepared by reacting 1-methylimidazole with chlorobutane. Gaseous hydrofluorocarbons (HFCs) such as fluoromethane, fluoroethane and 1,1,2,2-tetrafluoroethane are soluble in BMIMPF₆.

Application

1-Butyl-3-methylimidazolium hexafluorophosphate is an ionic liquid employed in many environmentally friendly reactions.

It can also be used as a medium for reactions such as:

• Ring-closing metathesis of diene and enyne substrates in the presence of a novel recyclable ruthenium carbene complex.
• Nickel(II)acetylacetonate catalyzed oxidation of aromatic aldehydes to the corresponding acids using dioxygen as the oxidant.
• Lipase-catalyzed enantioselective acylation of allylic alcohols.
• Allylation of aldehydes using tetraallylstannane to yield homoallylic alcohols.

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315 - H319
• Precautionary Statements: P264 - P280 - P302 + P352 - P305 + P351 + P338 - P332 + P313 - P337 + P313
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2
• Storage Class Code: 10 - Combustible liquids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves