710466

Sigma-Aldrich

Bis(2-methoxyphenyl)phosphine

97%

Synonym(s):
Di-o-anisylphosphine
Empirical Formula (Hill Notation):
C14H15O2P
CAS Number:
Molecular Weight:
246.24
MDL number:
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

97%

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

mp

86-90 °C

functional group

phosphine

SMILES string

COc1ccccc1Pc2ccccc2OC

InChI

1S/C14H15O2P/c1-15-11-7-3-5-9-13(11)17-14-10-6-4-8-12(14)16-2/h3-10,17H,1-2H3

InChI key

HFEAMIKDDWKNAG-UHFFFAOYSA-N

Application

Reactant for:
  • Allylation of phenols
  • Synthesis of neutral rhodium(I) complexes
  • Dinuclear Pd(II) complexes bearing bis-bidentate tetraphos ligands
  • CO-ethylene copolymerization reactions
  • Suzuki-Miyaura reaction for synthesis of alkyl derivatives phosphine sulfonate (P-O) ligands

Packaging

250 mg in glass bottle

Pictograms

FlameExclamation mark

Signal Word

Warning

Hazard Statements

Target Organs

Respiratory system

RIDADR

UN1325 - class 4.1 - PG 2 - Flammable solids, organic, n.o.s., HI: all

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis

Certificate of Origin

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