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711071

Sigma-Aldrich

Bis[tris(2-methylphenyl)phosphine]palladium

97%, powder

Synonym(s):

Bis(tris(2-tolyl)phosphine)palladium, Pd[(o-tol)3P]2

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About This Item

Empirical Formula (Hill Notation):
C42H42P2Pd
CAS Number:
Molecular Weight:
715.15
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

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Product Name

Bis[tris(2-methylphenyl)phosphine]palladium, 97%

Quality Level

assay

97%

form

powder

reaction suitability

core: palladium
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Cross Couplings
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

mp

220-225 °C

storage temp.

−20°C

SMILES string

[Pd].Cc1ccccc1P(c2ccccc2C)c3ccccc3C.Cc4ccccc4P(c5ccccc5C)c6ccccc6C

InChI

1S/2C21H21P.Pd/c2*1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3;/h2*4-15H,1-3H3;

InChI key

CUBIJGNGGJBNOC-UHFFFAOYSA-N

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1 of 4

This Item
667315900701759163
reaction suitability

core: palladium, reaction type: Cross Couplings, reaction type: Hiyama Coupling, reaction type: Sonogashira Coupling, reaction type: Suzuki-Miyaura Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Negishi Coupling, reagent type: catalyst, reaction type: Stille Coupling, reaction type: Heck Reaction

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

reaction suitability

-

reaction suitability

core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst

assay

97%

assay

-

assay

95%

assay

85%

form

powder

form

solid

form

powder or crystals

form

solid

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

storage temp.

−20°C

storage temp.

-

storage temp.

-

storage temp.

-

mp

220-225 °C

mp

176.7-187.1 °C

mp

-

mp

159-191 °C (decomposition)

Application

Catalyst for:
  • Palladium-catalyzed cross-coupling reactions and aminations
  • Kumada coupling
  • Arylation
  • Heck coupling

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Professor Hartwig's research focuses on the discovery and understanding of new reactions catalyzed by transition metal complexes.

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