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714836

Iodine monochloride solution

1 M in acetic acid

Synonym(s):

Chloroiodide solution, Wijs solution

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100 ML

$197.00

$197.00


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About This Item

Linear Formula:
ICl
CAS Number:
Molecular Weight:
162.36
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3587194
Form:
solution

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InChI key

QZRGKCOWNLSUDK-UHFFFAOYSA-N

SMILES string

ClI

InChI

1S/ClI/c1-2

form

solution

concentration

1 M in acetic acid

density

1.143 g/mL at 25 °C

Quality Level

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This Item
291048208221402990
Quality Level

100

Quality Level

100

Quality Level

200

Quality Level

200

density

1.143 g/mL at 25 °C

density

1.42 g/mL at 25 °C

density

3.24 g/mL at 25 °C (lit.)

density

3.24 g/mL at 25 °C (lit.)

form

solution

form

liquid

form

solid or liquid

form

solid or liquid

concentration

1 M in acetic acid

concentration

0.95-1.10 M (by Na2S2O3, titration), 1.0 M in methylene chloride

concentration

-

concentration

-

General description

Iodine monochloride is an inorganic reagent used in the iodination and chloroiodination of aromatic and unsaturated compounds, respectively. It is also used to cleave carbon-metal bonds.

Application

Iodine monochloride can be used:
  • As a reagent in the preparation of α-iodo β-ketosulfones from β-ketosulfones.
  • In the synthesis of 3-(4-bromo-2-methylphenyl)-4-iodosydnone, which is further used to prepare substituted pyrazoles.

pictograms

FlameCorrosion

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

105.1 °F

flash_point_c

40.6 °C


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Synthesis of α-iodo β-ketosulfones and α-iodo methylsulfones using iodine monochloride
Suryakiran N, et al.
Tetrahedron Letters, 47(26), 4319-4323 (2006)
Iodine monochloride
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2013)
Steric effects on the sydnones reactivity. New sydnones and pyrazoles
Dumitracscu F, et al.
ARKIVOC (Gainesville, FL, United States), 2(26), 80-86 (2002)
K R Siebenlist et al.
Biochemistry, 39(46), 14171-14175 (2000-11-23)
There are conflicting ideas regarding the location of the carboxyl-terminal regions of cross-linked gamma-chain dimers in double-stranded fibrin fibrils. Some investigators believe that the chains are always oriented longitudinally along each fibril strand and traverse the contacting ends of abutting
Zan Qu et al.
Journal of hazardous materials, 183(1-3), 132-137 (2010-08-03)
The removal of Hg(0) by the homogenous gas-phase reaction and particle-induced reaction was investigated under various conditions. Iodine monochloride was found to be efficient for Hg(0) oxidation, with the apparent 2nd-order rate constant of about 10.5(±0.3)×10(-17) cm(3) molecules(-1) s(-1) and

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