717398

All Photos(1)

(S)[(S_p)-2-(Diphenylphosphino)ferrocenyl]-4-isopropyloxazoline

97%

All Photos(1)

Synonym(s):

(S_p)-1-(Diphenylphosphino)-2-[(4S)-4-isopropyl-2-oxazolyl]ferrocene

Empirical Formula (Hill Notation):

C₂₈H₂₈FeNOP

CAS Number:

163169-29-7

Molecular Weight:

481.35

MDL number:

MFCD15144869

PubChem Substance ID:

329763485

NACRES:

NA.22

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Sigma-Aldrich

688495

(S)-4-tert-Butyl-2-[2-(diphenylphosphino)phenyl]-2-oxazoline

Sigma-Aldrich

72575

(R)-(+)-2-[2-(Diphenylphosphino)phenyl]-4-isopropyl-2-oxazoline

Sigma-Aldrich

688533

(S)-2-[2-[Bis(2-tolyl)phosphino]phenyl]-4-tert-butyl-2-oxazoline

Sigma-Aldrich

729264

(S)-2-(1-Diphenylphosphino-2-methylpropan-2-yl)-4-isopropyl-4,5-dihydrooxazole

Sigma-Aldrich

88717

(R)-1-[(S_P)-2-(Diphenylphosphino)ferrocenyl]ethyldicyclohexylphosphine

Sigma-Aldrich

719641

(4S)-2-[2-(diphenylphosphino)phenyl]-4,5-dihydro-5,5-dimethyl-4-(1-methylethyl)-oxazole

Sigma-Aldrich

88719

(R)-1-[(S_P)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine

Sigma-Aldrich

743585

(S)-(−)-1-(2-Diphenylphosphino-1-naphthyl)isoquinoline

Sigma-Aldrich

682322

(R)-N-Methyl-N-diphenylphosphino-1-[(S)-2-diphenylphosphino)ferrocenyl]ethylamine

Sigma-Aldrich

683094

HS157

Quality Level

100

Assay

97%

form

solid

optical activity

[α]20/D 366°, c = 0.1 in chloroform

mp

158-162 °C

SMILES string

[Fe].[CH]1[CH][CH][CH][CH]1.CC(C)[C@H]2COC(=N2)[C]3[CH][CH][CH][C]3P(c4ccccc4)c5ccccc5

InChI

1S/C23H23NOP.C5H5.Fe/c1-17(2)21-16-25-23(24-21)20-14-9-15-22(20)26(18-10-5-3-6-11-18)19-12-7-4-8-13-19;1-2-4-5-3-1;/h3-15,17,21H,16H2,1-2H3;1-5H;/t21-;;/m1../s1

InChI key

FELCHLOAEMNOQM-GHVWMZMZSA-N

Related Categories

Chiral Catalysts & Ligands

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This Item	07541	88720	697354
Sigma-Aldrich 717398 (S)[(S_p)-2-(Diphenylphosphino)ferrocenyl]-4-isopropyloxazoline	Sigma-Aldrich 07541 (R_P)-1-Dicyclohexylphosphino-2-[(R)-α-(dimethylamino)-2-(dicyclohexylphosphino)benzyl]ferrocene	Sigma-Aldrich 88720 (S)-1-[(R_P)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine	Sigma-Aldrich 697354 (R_p)-1-[(1S)-(1-Aminoethyl)]-2-(diphenylphosphino)ferrocene
assay 97%	assay ≥97%	assay ≥97%	assay 97%
form solid	form -	form powder	form powder
optical activity [α]20/D 366°, c = 0.1 in chloroform	optical activity -	optical activity [α]20/D +410±15°, c = 0.5 in chloroform	optical activity -
mp 158-162 °C	mp -	mp -	mp 131-135 °C
Quality Level 100	Quality Level 100	Quality Level 100	Quality Level 100

Application

(S)[(S_p)-2-(Diphenylphosphino)ferrocenyl]-4-isopropyloxazoline can be used as a chiral ligand in the synthesis of rhodium, iridium, ruthenium, and osmium metal complexes.

Legal Information

Sold under license from Kanata Chemical Technologies Inc. for research purposes only.

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis

Enter Lot Number to search for Certificate of Analysis (COA).

Certificate of Origin

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(S)[(S_p)-2-(Diphenylphosphino)ferrocenyl]-4-isopropyloxazoline

97%

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