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718114

Manganese(II) chloride bis(lithium chloride) complex solution

0.5 M in THF, liquid, density: 95%6 g/mL at 25 °C

Synonym(s):

Lithium tetrachloromanganate(II) solution, Lithium chloromanganate(II), Lithium manganese chloride, Manganese(II) chloride bis(lithium chloride) complex solution

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Size/SKUAvailabilityPrice
100 mL
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$231.00

About This Item

Linear Formula:
Li2MnCl4
CAS Number:
Molecular Weight:
210.63
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
MDL number:

$231.00


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Product Name

Manganese(II) chloride bis(lithium chloride) complex solution, 0.5 M in THF, density: 0.956 g/mL at 25 °C

form

liquid

Quality Segment

reaction suitability

core: manganese, reagent type: catalyst

concentration

0.5 M in THF

density

0.956 g/mL at 25 °C

SMILES string

[Li+].[Li+].Cl[Mn--](Cl)(Cl)Cl

InChI

1S/4ClH.2Li.Mn/h4*1H;;;/q;;;;2*+1;+2/p-4

InChI key

VJOUQNFWQPCDPE-UHFFFAOYSA-J

Application

Catalyst for homocoupling of Grignard reagents using atmospheric oxygen as an oxidant

Reactant for:
  • Transmetalation reactions
  • Nickel-imidazolium carbene-catalyzed coupling reactions

Reagent for the preparation of Rieke manganese

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This Item
703559328146244589
description

0.5 M in THF, density: 0.956 g/mL at 25 °C

description

0.6 M in THF

description

flakes, 98%

description

powder and chunks, ≥99% trace metals basis

reaction suitability

reagent type: catalyst, core: manganese

reaction suitability

reagent type: catalyst
core: lanthanum
reaction type: Grignard Reaction

reaction suitability

core: manganese, reagent type: catalyst

reaction suitability

core: manganese

form

liquid

form

liquid

form

flakes

form

powder and chunks

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

200

density

0.956 g/mL at 25 °C

density

1.05 g/mL at 25 °C

density

2.98 g/mL at 25 °C (lit.)

density

2.98 g/mL at 25 °C (lit.)

concentration

0.5 M in THF

concentration

16 % (w/w), 0.6 M in THF

concentration

-

concentration

-


Signal Word

Danger

Target Organs

Central nervous system, Respiratory system

supp_hazards

Storage Class

3 - Flammable liquids

Flash Point (°F)

1.4 °F - closed cup

Flash Point (°C)

-17.0 °C - closed cup

Hazard Classifications

Acute Tox. 4 Oral - Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3



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