(S)-(−)-4-Methoxy-α-methylbenzylamine

Name: (<I>S</I>)-(−)-4-Methoxy-α-methylbenzylamine
Brand: ALDRICH

ChiPros^®, produced by BASF, 99%

Synonym(s):

(S)-(−)-1-(4-Methoxyphenyl)ethylamine

Slide 1 of 1

Sign Into View Organizational & Contract Pricing

Select a Size

Pricing and availability is not currently available.

About This Item

Empirical Formula (Hill Notation):

C₉H₁₃NO

CAS Number:

41851-59-6

Molecular Weight:

151.21

Beilstein/REAXYS Number:

3196456

MDL number:

MFCD00671660

UNSPSC Code:

12352112

PubChem Substance ID:

329764254

NACRES:

NA.22

Key Documents

View All Documentation

Quality Level

100

assay

≥98.5% (GC)
99%

form

liquid

optical purity

enantiomeric excess: ≥98.5%

density

1.024 g/mL at 20 °C (lit.)

functional group

amine

SMILES string

COc1ccc(cc1)[C@H](C)N

InChI

1S/C9H13NO/c1-7(10)8-3-5-9(11-2)6-4-8/h3-7H,10H2,1-2H3/t7-/m0/s1

InChI key

JTDGKQNNPKXKII-ZETCQYMHSA-N

Looking for similar products? Visit Product Comparison Guide

Related Categories

Catalysts

Chiral Catalysts & Ligands

Compare Similar Items

View Full Comparison

Show Differences

1 of 3

This Item	726842	95889
Sigma-Aldrich 726656 (S)-(−)-4-Methoxy-α-methylbenzylamine	Sigma-Aldrich 726842 (R)-(+)-4-Methoxy-α-methylbenzylamine	Sigma-Aldrich 95889 (S)-(−)-4-Methoxy-α-methylbenzylamine
assay ≥98.5% (GC), 99%	assay ≥98.5% (GC), 99%	assay ≥98.0% (sum of enantiomers, GC)
Quality Level 100	Quality Level 100	Quality Level 100
form liquid	form liquid	form liquid
density 1.024 g/mL at 20 °C (lit.)	density 1.024 g/mL at 20 °C (lit.)	density 1.024 g/mL at 20 °C (lit.)
grade produced by BASF	grade produced by BASF	grade -
optical purity enantiomeric excess: ≥98.5%	optical purity enantiomeric excess: ≥98.5%	optical purity enantiomeric ratio: ≥97.5:2.5 (GC)

Application

(S)-(−)-4-Methoxy-α-methylbenzylamine is employed in the synthesis of S(+)-4-(1-phenylethylamino)quinazolines,[1] as human immunoglobuline E inhibitor and haloaryl-β-amino acids.[2] It is also used as a precursor to prepare chiral intermediate in the total synthesis of solanoeclepin A.[3]

Legal Information

ChiPros is a registered trademark of BASF SE

pictograms

GHS05

signalword

Danger

hcodes

H314

pcodes

P280 - P305 + P351 + P338 - P310

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Novel Synthesis of the ABC Rings of Solanoeclepin A.

Lin Y T, et al.

Organic Letters, 16(22), 5948-5951 (2014)

S (+)-4-(1-phenylethylamino) quinazolines as inhibitors of human immunoglobuline E synthesis: potency is dictated by stereochemistry and atomic point charges at N-1.

Berger M, et al.

Journal of Medicinal Chemistry, 44(18), 3031-3038 (2001)

The asymmetric synthesis of β-haloaryl-β-amino acid derivatives.

Bull S D, et al.

Synlett, 2000(09), 1257-1260 (2000)

Articles

ChiPros Chiral Amines

Chiral amines play an important role in stereoselective organic synthesis. They are used directly as resolving agents, building blocks, or chiral auxiliaries.

Questions

Reviews

No rating value

Active Filters

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service