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727695

Sigma-Aldrich

1-Allyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide

≥98.5% (HPLC)

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Synonym(s):
AMIMTFSI
Empirical Formula (Hill Notation):
C9H11F6N3O4S2
CAS Number:
655249-87-9
Molecular Weight:
403.32
MDL number:
MFCD11109343
PubChem Substance ID:
329764339
NACRES:
NA.22

Quality Level

100

Assay

≥98.5% (HPLC)

form

liquid

impurities

≤1% water

SMILES string

C[n+]1ccn(CC=C)c1.FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F

InChI

1S/C7H11N2.C2F6NO4S2/c1-3-4-9-6-5-8(2)7-9;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8/h3,5-7H,1,4H2,2H3;/q+1;-1

InChI key

DHMWATGUEVQTIY-UHFFFAOYSA-N

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7277094396177896
1-Allyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ≥98.5% (HPLC)

Sigma-Aldrich

727695

1-Allyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide

1-Allyl-3-methylimidazolium dicyanamide ≥98.5% (HPLC)

Sigma-Aldrich

727709

1-Allyl-3-methylimidazolium dicyanamide

1-Allyl-3-methylimidazolium chloride ≥97.0% (HPLC)

Sigma-Aldrich

43961

1-Allyl-3-methylimidazolium chloride

1-Butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ≥98.0% (HPLC)

Sigma-Aldrich

77896

1-Butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide

form

liquid

form

liquid

form

crystals

form

liquid

impurities

≤1% water

impurities

≤1.0% water

impurities

-

impurities

≤0.5% water

General description

1-Allyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide is an ionic liquid that can be prepared by reacting 1-allyl-3-methylimidazolium chloride and lithium bis(trifluoromethylsulfonyl)imide under microwave conditions.

Application

1-Allyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide can be used to prepare AMIMTFSI-propylene carbonate based electrolyte, with potential application in lithium-ion batteries. It also finds application in alkanes/alkenes separation process. AMIMTFSI can be used as a surface protector to develop luminescent silicon nanoparticles.

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H319

Precautionary Statements

P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

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Synthesis and properties of pyrrolidinium and piperidinium bis (trifluoromethanesulfonyl) imide ionic liquids with allyl substituents
Yim, Tae Eun, et al.
J. Korean Chem. Soc., 28.9, 1567-1567 (2007)
Liquid?liquid equilibrium data for {heptane+ aromatic+ 1-(2-hydroxyethyl)-3-methylimidazolium bis (trifluoromethylsulfonyl) imide ([hemim][NTf2])} ternary systems
Ebrahimi, M., et al.
Journal of Chemical and Engineering Data, 59.2, 197-204 (2014)
Mixtures of unsaturated imidazolium based ionic liquid and organic carbonate as electrolyte for Li-ion batteries.
Wang M, et al.
Electrochimica Acta, 95, 301-307 (2013)
Luminescent silicon nanoparticles covered with ionic liquid.
Miyano M, et al.
Materials Letters, 141, 359-361 (2015)
Recent advances of ionic liquids in separation science and mass spectrometry
Joshi, Manishkumar D., and Jared L. Anderson.
Royal Society of Chemistry Advances, 2.13, 5470-5484 (2012)
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