745480

Zinc isopropylsulfinate

95%

• Synonym(s): Baran Isopropylation Reagent, Baran IPS Reagent, Bis((isopropylsulfinyl)oxy)zinc, IPS
• Empirical Formula (Hill Notation): C₆H₁₄O₄S₂Zn
• CAS Number: 1416821-55-0
• Molecular Weight: 279.69
• MDL number: MFCD24386390
• PubChem Substance ID: 329764984
• NACRES: NA.22

Properties

• Quality Level: 100
• assay: 95%
• form: solid
• reaction suitability: reaction type: Allylation; reagent type: catalyst; reaction type: C-H Activation; reagent type: diversification reagent
• mp: 161-166 °C
• SMILES string: CC(C)S(=O)O[Zn]OS(=O)C(C)C
• InChI: 1S/2C3H8O2S.Zn/c2*1-3(2)6(4)5;/h2*3H,1-2H3,(H,4,5);/q;;+2/p-2
• InChI key: PEEMMWYYSHSBTQ-UHFFFAOYSA-L

Description

Application

Zinc isopropylsulfinate (IPS) is part of a zinc sulfinate toolbox developed by Phil Baran for the simple and rapid diversification of heterocycles.


Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles

Learn More at the Professor and Product Portal of Professor Phil S. Baran.

Packaging

100 mg

1, 10 g in glass bottle

Linkage

Frequently Asked Questions are available for this Product.

Preparation Note

may contain up to 1 mole eq ZnCl₂

Other Notes

Previously sold under product number L511161

Safety Information

• Pictograms: GHS05,GHS07,GHS09
• Signal Word: Danger
• Hazard Statements: H314 - H335 - H410
• Precautionary Statements: P260 - P271 - P273 - P280 - P303 + P361 + P353 - P305 + P351 + P338
• Hazard Classifications: Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 8A - Combustible, corrosive hazardous materials
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable