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For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf
745979
tBuBrettPhos Pd G3
96%, solid
Synonym(s):
tert-BuBrettPhos-Pd-G3, [(2-Di-tert-butylphosphino-3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl)-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate
Select a Size
| Size/SKU | Availability | Price |
|---|---|---|
100 mg | Available to ship onJuly 22, 2026fromMILWAUKEE | $91.40 $68.55 |
500 mg | Available to ship onJuly 22, 2026fromMILWAUKEE | $270.00 $202.50 |
1 g | Estimated to ship onSeptember 07, 2026fromMILWAUKEE | $375.00 |
2 g | Available to ship onJuly 22, 2026fromMILWAUKEE | $731.00 |
5 g | Estimated to ship onSeptember 07, 2026fromMILWAUKEE | $1,300.00 |
About This Item
$68.55
List Price$91.40Save 25%Available to ship onJuly 22, 2026Details
Product Name
tBuBrettPhos Pd G3, 96%
Quality Segment
product line
Buchwald precatalyst Generation 3
assay
96%
form
solid
feature
generation 3
reaction suitability
core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplings
mp
119-131 °C
functional group
phosphine
SMILES string
COC1=CC=C(C(P(C(C)(C)C)C(C)(C)C)=C1C2=C(C=C(C=C2C(C)C)C(C)C)C(C)C)OC.NC3=C(C=CC=C3)C4=C(C=CC=C4)[Pd]OS(C)(=O)=O
InChI
1S/C31H49O2P.C12H10N.CH4O3S.Pd/c1-19(2)22-17-23(20(3)4)27(24(18-22)21(5)6)28-25(32-13)15-16-26(33-14)29(28)34(30(7,8)9)31(10,11)12;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h15-21H,1-14H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1
InChI key
GAQPAUHHECNHNS-UHFFFAOYSA-M
General description
Application
For small scale and high throughput uses, product is also available as ChemBeads (928313)
1 of 1
This Item | |||
|---|---|---|---|
| description 96% | description - | description 98% | description 98% |
| assay 96% | assay - | assay 98% | assay 98% |
| reaction suitability core: palladium, reaction type: Heck Reaction, reaction type: Negishi Coupling, reaction type: Stille Coupling, reagent type: catalyst | reaction suitability - | reaction suitability - | reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst |
| form solid | form solid | form solid | form solid |
| functional group phosphine | functional group - | functional group phosphine | functional group phosphine |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| mp 119-131 °C | mp - | mp 130-140 °C | mp 188-196 °C (decomposition) |
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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