746304

Sigma-Aldrich

S,S-Dibenzyl trithiocarbonate

97%

Synonym(s):
DBTTC, Carbonotrithioic acid bis(phenylmethyl) ester, NSC 33081, Carbonic acid, trithio-, dibenzyl ester, Dibenzyl carbonotrithioate
Empirical Formula (Hill Notation):
C15H14S3
CAS Number:
Molecular Weight:
290.47
MDL number:
PubChem Substance ID:
NACRES:
NA.23
Pricing and availability is not currently available.

Quality Level

assay

97%

mp

29-33 °C

storage temp.

2-8°C

SMILES string

S=C(SCC1=CC=CC=C1)SCC2=CC=CC=C2

InChI

1S/C15H14S3/c16-15(17-11-13-7-3-1-4-8-13)18-12-14-9-5-2-6-10-14/h1-10H,11-12H2

InChI key

LAKYXBYUROTWBI-UHFFFAOYSA-N

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Related Categories

Packaging

1, 5 g in glass bottle

Application

Trithiocarbonate-based RAFT agent used as a bifunctional Chain Transfer Agent (CTA) in RAFT polymerization of block copolymers for drug delivery. Provides good control of polymerization of vinyl monomers, including styrene, methacrylate, and acrylamide.

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

RIDADR

NONH for all modes of transport

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis
Certificate of Origin
Synthesis of stimuli-sensitive copolymers by RAFT polymerization: potential candidates as drug delivery systems
Tebaldi, M. L., Leal, D. A., Montoro, S. R., & Petzhold, C.
Journal of Materials Research (2014)
Kiwon Hwang et al.
Polymers, 12(4) (2020-04-23)
Tread is an important component that directly affects the performance of passenger car radial (PCR) tires. Styrene-butadiene rubber (SBR) is mainly used for tire tread and it includes solution styrene-butadiene rubber (SSBR) and emulsion styrene-butadiene rubber (ESBR). Although SSBR is...
Thiocarbonylthio compounds (SC (Z) SR) in free radical polymerization with reversible addition-fragmentation chain transfer (RAFT polymerization).
Chiefari, J., Mayadunne, R. T., Moad, C. L., Moad, G., Rizzardo, E., Postma, A., & Thang, S. H.
Macromolecules, 36(7), 2273-2283 (2003)
One-step synthesis of block copolymers using a hydroxyl-functionalized trithiocarbonate RAFT agent as a dual initiator for RAFT polymerization and ROP
Kang, H. U., Yu, Y. C., Shin, S. J., & Youk, J. H.
Journal of Polymer Science Part A: Polymer Chemistry, 51(4), 774-779 (2013)
Articles
The supply of low cost, high purity and effective Reversible addition−fragmentation chain-transfer (RAFT) Agents is the essential element in the industrial implementation of RAFT polymerization technology.
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Over the past two decades, the rapid advance of controlled living polymerization (CLP) techniques.
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The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.
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