747777

[Ru(bpz)₃][PF₆]₂

95%

• Synonym(s): Tris(2,2′-bipyrazine)ruthenium bis(hexafluorophosphate), Tris(2,2′-bipyrazine-N1,N1′)ruthenium(II) hexafluorophosphate
• Empirical Formula (Hill Notation): C₂₄H₁₈F₁₂N₁₂P₂Ru
• CAS Number: 80907-56-8
• Molecular Weight: 865.48
• NACRES: NA.22

Properties

• Quality Level: 100
• assay: 95%
• form: powder
• reaction suitability: core: ruthenium; reaction type: Photocatalysis; reagent type: catalyst
• impurities: may contain ca. 5% acetonitrile
• mp: 162-210 °C (The MP data is a DECOMP) (lit.)
• SMILES string: [N]12=CC=NC=C1C3=CN=CC=[N]3[Ru]24([N]5=CC=NC=C5C6=CN=CC=[N]64)([N]7=CC=NC=C78)[N]9=C8C=NC=C9
• InChI: 1S/3C8H6N4.Ru/c3*1-3-11-7(5-9-1)8-6-10-2-4-12-8;/h3*1-6H;
• InChI key: VEEMVPAUPIJPLA-UHFFFAOYSA-N

Description

General description

[Ru(bpz)₃][PF₆]₂ can be prepared from 2-iodopyrazine.

Application

[Ru(bpz)₃][PF₆]₂ may be employed as a photocatalyst during the preparation of cyclopentylamine derivatives, via visible light-assisted cycloaddition reaction of N-arylcyclopropylamines with styrene derivatives. It may also be employed for the photocatalytic synthesis of trans-substituted cyclohexene derivative.

Packaging

50, 100 mg in glass bottle

Safety Information

• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable