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747777

Sigma-Aldrich

[Ru(bpz)3][PF6]2

95%

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Synonym(s):
Tris(2,2′-bipyrazine)ruthenium bis(hexafluorophosphate), Tris(2,2′-bipyrazine-N1,N1′)ruthenium(II) hexafluorophosphate
Empirical Formula (Hill Notation):
C24H18F12N12P2Ru
CAS Number:
Molecular Weight:
865.48
NACRES:
NA.22

Quality Level

assay

95%

form

powder

reaction suitability

core: ruthenium
reaction type: Photocatalysis
reagent type: catalyst

impurities

may contain ca. 5% acetonitrile

mp

162-210 °C (The MP data is a DECOMP) (lit.)

SMILES string

[N]12=CC=NC=C1C3=CN=CC=[N]3[Ru]24([N]5=CC=NC=C5C6=CN=CC=[N]64)([N]7=CC=NC=C78)[N]9=C8C=NC=C9

InChI

1S/3C8H6N4.Ru/c3*1-3-11-7(5-9-1)8-6-10-2-4-12-8;/h3*1-6H;

InChI key

VEEMVPAUPIJPLA-UHFFFAOYSA-N

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1 of 4

This Item
904953904945903426
vibrant-m

747777

[Ru(bpz)3][PF6]2

vibrant-m

904953

[Ru(dtbbpy)3](PF6)2

vibrant-m

904945

[Ru(dmbpy)3](PF6)2

vibrant-m

903426

Ru(p-CF3-bpy)3 (BF4)2

reaction suitability

core: ruthenium, reagent type: catalyst, reaction type: Photocatalysis

reaction suitability

core: ruthenium, reagent type: catalyst
reaction type: Photocatalysis

reaction suitability

core: ruthenium, reagent type: catalyst
reaction type: Photocatalysis

reaction suitability

core: ruthenium, reagent type: catalyst
reaction type: Photocatalysis

Quality Level

100

Quality Level

-

Quality Level

-

Quality Level

-

form

powder

form

powder or crystals

form

powder or crystals

form

powder or crystals

mp

162-210 °C (The MP data is a DECOMP) (lit.)

mp

>300 °C

mp

>300 °C

mp

>300 °C

impurities

may contain ca. 5% acetonitrile

impurities

-

impurities

-

impurities

-

General description

[Ru(bpz)3][PF6]2 can be prepared from 2-iodopyrazine.

Application

[Ru(bpz)3][PF6]2 may be employed as a photocatalyst during the preparation of cyclopentylamine derivatives, via visible light-assisted cycloaddition reaction of N-arylcyclopropylamines with styrene derivatives. It may also be employed for the photocatalytic synthesis of trans-substituted cyclohexene derivative.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Knochel P and Molander GA
Comprehensive Organic Synthesis, 275-275 (2014)
Rodriguez J and Bonne D.
Stereoselective Multiple Bond-Forming Transformations in Organic Synthesis, 203-203 (2015)
Danielle M Schultz et al.
Beilstein journal of organic chemistry, 11, 61-65 (2015-02-12)
There has been a recent surge of interest in the use of transition metal polypyridyl complexes as visible light-absorbing photocatalysts for synthetic applications. Among the most attractive features of this approach is the availability of many known complexes with well-characterized

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