747777

Sigma-Aldrich

[Ru(bpz)3][PF6]2

95%

Synonym(s):
Tris(2,2′-bipyrazine)ruthenium bis(hexafluorophosphate), Tris(2,2′-bipyrazine-N1,N1′)ruthenium(II) hexafluorophosphate
Empirical Formula (Hill Notation):
C24H18F12N12P2Ru
CAS Number:
Molecular Weight:
865.48
NACRES:
NA.22

Quality Level

assay

95%

reaction suitability

core: ruthenium
reaction type: Photocatalysis
reagent type: catalyst

impurities

may contain ca. 5% acetonitrile

mp

162-210 °C (The MP data is a DECOMP) (lit.)

SMILES string

[N]12=CC=NC=C1C3=CN=CC=[N]3[Ru]24([N]5=CC=NC=C5C6=CN=CC=[N]64)([N]7=CC=NC=C78)[N]9=C8C=NC=C9

InChI

1S/3C8H6N4.Ru/c3*1-3-11-7(5-9-1)8-6-10-2-4-12-8;/h3*1-6H;

InChI key

VEEMVPAUPIJPLA-UHFFFAOYSA-N

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General description

[Ru(bpz)3][PF6]2 can be prepared from 2-iodopyrazine.

Application

[Ru(bpz)3][PF6]2 may be employed as a photocatalyst during the preparation of cyclopentylamine derivatives, via visible light-assisted cycloaddition reaction of N-arylcyclopropylamines with styrene derivatives. It may also be employed for the photocatalytic synthesis of trans-substituted cyclohexene derivative.

Packaging

50, 100 mg in glass bottle

storage_class_code

13 - Non Combustible Solids

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis

Certificate of Origin

Rodriguez J and Bonne D.
Stereoselective Multiple Bond-Forming Transformations in Organic Synthesis, 203-203 (2015)
Knochel P and Molander GA
Comprehensive Organic Synthesis, 275-275 (2014)
Danielle M Schultz et al.
Beilstein journal of organic chemistry, 11, 61-65 (2015-02-12)
There has been a recent surge of interest in the use of transition metal polypyridyl complexes as visible light-absorbing photocatalysts for synthetic applications. Among the most attractive features of this approach is the availability of many known complexes with well-characterized...

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