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748196

Sigma-Aldrich

(1R,2R)-2-Amino-1-phenylpropyldiphenylphosphine

Empirical Formula (Hill Notation):
C21H22NP
CAS Number:
Molecular Weight:
319.38
MDL number:
PubChem Substance ID:
NACRES:
NA.22

form

solid

Quality Level

optical activity

[α]/D -138.0°, c = 0.5% in chloroform

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

mp

105-109 °C

functional group

phosphine

storage temp.

20-25°C

SMILES string

C[C@@H](N)[C@H](P(c1ccccc1)c2ccccc2)c3ccccc3

InChI

1S/C21H22NP/c1-17(22)21(18-11-5-2-6-12-18)23(19-13-7-3-8-14-19)20-15-9-4-10-16-20/h2-17,21H,22H2,1H3/t17-,21+/m1/s1

InChI key

JWZAIGGNEGTDMG-UTKZUKDTSA-N

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This Item
716685748242331899
form

solid

form

solid

form

solid

form

solid

optical activity

[α]/D -138.0°, c = 0.5% in chloroform

optical activity

[α]22/D −55.0°, c = 0.5 in chloroform

optical activity

[α]22/D 59.0°, c = 0.5% in chloroform

optical activity

[α]25/D −7.0°, c = 0.6 in ethanol

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

reaction suitability

-

reaction suitability

-

reaction suitability

-

mp

105-109 °C

mp

120-127 °C

mp

75-81 °C

mp

142-144 °C (lit.)

functional group

phosphine

functional group

-

functional group

-

functional group

-

storage temp.

20-25°C

storage temp.

-

storage temp.

-

storage temp.

-

Pictograms

Corrosion

Signal Word

Danger

Hazard Statements

Hazard Classifications

Skin Corr. 1B

Storage Class Code

8A - Combustible, corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis

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Certificate of Origin

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