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MilliporeSigma

751855

Hydrazine solution

1 M in acetonitrile

Synonym(s):

Hydrazine, Nitrogen hydride

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100 ML

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About This Item

Linear Formula:
NH2NH2
CAS Number:
302-01-2
Molecular Weight:
32.05
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
329766244
MDL number:
MFCD00011417
Beilstein/REAXYS Number:
878137

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Product Name

Hydrazine solution, 1 M in acetonitrile

InChI key

OAKJQQAXSVQMHS-UHFFFAOYSA-N

SMILES string

NN

InChI

1S/H4N2/c1-2/h1-2H2

form

liquid

concentration

1 M in acetonitrile

refractive index

n20/D 1.348

density

0.779 g/mL at 25 °C

functional group

hydrazine

Quality Level

100

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This Item
433632901596309400
Hydrazine solution 1 M in acetonitrile

Sigma-Aldrich

751855

Hydrazine solution

Hydrazine solution 1.0 M in THF

Sigma-Aldrich

433632

Hydrazine solution

Hydrazine solution 1.0 M in ethanol

Sigma-Aldrich

901596

Hydrazine solution

Hydrazine solution 35 wt. % in H2O

Sigma-Aldrich

309400

Hydrazine solution

Quality Level

100

Quality Level

100

Quality Level

-

Quality Level

100

density

0.779 g/mL at 25 °C

density

0.886 g/mL at 25 °C

density

0.7934 g/mL

density

1.011 g/mL at 25 °C

form

liquid

form

liquid

form

liquid

form

liquid

refractive index

n20/D 1.348

refractive index

-

refractive index

n/D 1.3666

refractive index

-

concentration

1 M in acetonitrile

concentration

1.0 M in THF

concentration

1.0 M in ethanol

concentration

35 wt. % in H2O

functional group

hydrazine

functional group

hydrazine

functional group

hydrazine

functional group

hydrazine

Application

Hydrazine solution (in acetonitrile) can be used as a reducing source for the reduction of carbon-carbon multiple bonds in alkenes, alkynes, and α,β-unsaturated esters using metal-organic frameworks (MOFs) as heterogeneous catalysts. It is also used in the synthesis of polysubstituted 2-aminoimidazoles from 2-aminopyrimidines and α-bromocarbonyl compounds.

General description

Hydrazine (N2H4) solution is a common reducing agent and a versatile reagent in organic synthesis. It can reduce a variety of functional groups like ketones, aldehydes, imines, nitro compounds, azides & nitrates to their corresponding amines. It also serves as a source of nitrogen in the synthesis of heterocyclic compounds, such as pyrazoles and pyrazolines.

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Pricing

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Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 2 - Carc. 1B - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - Skin Sens. 1

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

41.0 °F

flash_point_c

5 °C

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Certificates of Analysis (COA)

Lot/Batch Number
MKCL9831
MKCM2130
MKCL0926
MKCL8237
MKCL7215

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D P Elder et al.
Journal of pharmaceutical and biomedical analysis, 54(5), 900-910 (2010-12-15)
This is the latest of a series of reviews focused on the analysis of genotoxic impurities. This review summarises the analytical approaches reported in the literature relating to hydrazine, hydrazines, hydrazides and hydrazones. It is intended to provide guidance for
Min Yuan et al.
Dalton transactions (Cambridge, England : 2003), (31)(31), 6078-6088 (2010-05-08)
A combination of unique solvent properties of hydrazine enables the direct dissolution of a range of metal chalcogenides at ambient temperature, rendering this an extraordinarily simple and soft synthetic approach to prepare new metal chalcogenide-based materials. The extended metal chalcogenide
M Vogel et al.
Fresenius' journal of analytical chemistry, 366(8), 781-791 (2001-03-03)
Hydrazine reagents are a well-known group of derivatizing agents for the determination of aldehydes and ketones in liquid and gaseous samples. Within this article, the most important hydrazine reagents are critically summarized, and their major applications in different fields, including
Nilay Hazari
Chemical Society reviews, 39(11), 4044-4056 (2010-06-24)
One of the most challenging problems in small molecule activation is the development of a homogeneous catalyst for converting dinitrogen into ammonia at ambient temperatures and atmospheric pressure. A catalytic cycle based on molybdenum that converts dinitrogen into ammonia has
Yinhu Wang et al.
Biosensors & bioelectronics, 43, 180-185 (2013-01-12)
We report a novel hydrogen peroxide (H2O2) and hydrazine sensor based on low-cost poly(vinylpyrrolidone)-protected silver nanocubes (PVP-AgNCs). The monodisperse silver nanocubes were prepared by adding a trace amount of sodium sulfide in the conventional polyol synthesis for fast reduction of
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