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752126

Sigma-Aldrich

Ethylmagnesium bromide solution

40% in 2-methyltetrahydrofuran

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Synonym(s):
Bromoethylmagnesium
Linear Formula:
CH3CH2MgBr
CAS Number:
Molecular Weight:
133.27
Beilstein/REAXYS Number:
3587203
MDL number:
PubChem Substance ID:
NACRES:
NA.22

form

liquid

Quality Level

concentration

40% in 2-methyltetrahydrofuran

density

1.140 g/mL at 25 °C

SMILES string

CC[Mg]Br

InChI

1S/C2H5.BrH.Mg/c1-2;;/h1H2,2H3;1H;/q;;+1/p-1

InChI key

TWTWFMUQSOFTRN-UHFFFAOYSA-M

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1 of 4

This Item
345105364673189871
vibrant-m

752126

Ethylmagnesium bromide solution

vibrant-m

345105

Ethylmagnesium bromide solution

vibrant-m

364673

Ethylmagnesium bromide solution

vibrant-m

189871

Ethylmagnesium bromide solution

density

1.140 g/mL at 25 °C

density

0.841 g/mL at 25 °C

density

1.010 g/mL at 25 °C

density

1.02 g/mL at 25 °C

form

liquid

form

-

form

-

form

-

concentration

40% in 2-methyltetrahydrofuran

concentration

1.0 M in tert-butyl methyl ether

concentration

1.0 M in THF

concentration

3.0 M in diethyl ether

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - Water-react 1

supp_hazards

Storage Class

4.3 - Hazardous materials, which set free flammable gases upon contact with water

wgk_germany

WGK 2

flash_point_f

12.2 °F - closed cup

flash_point_c

-11 °C - closed cup


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Janne E Tønder et al.
Organic & biomolecular chemistry, 2(10), 1447-1455 (2004-05-12)
Copper mediated allylic substitutions and conjugate additions to geranyl, cinnamyl and allylic indole compounds have been investigated with the aim of finding a method for the creation of the all-carbon quaternary centre present in the natural product lyngbyatoxin A. Reaction
M Wältermann et al.
Microbiology (Reading, England), 146 ( Pt 5), 1143-1149 (2000-06-01)
The triacylglycerol (TAG)-accumulating, hydrocarbon-degrading bacterium Rhodococcus opacus strain PD630 and chemically induced storage-deficient mutants derived from this strain were investigated for their capability to accumulate storage lipids in the cytoplasm during cultivation under nitrogen-limiting conditions. Acylglycerols were analysed by matrix-associated
T Nishiyama et al.
Chemical & pharmaceutical bulletin, 48(12), 1999-2002 (2001-01-06)
The direct alpha-bromination of various ketones using trifluoromethanesulfonic anhydride and Grignard reagent or magnesium bromide in ether gave the corresponding alpha-bromo ketones in moderate to good yields under mild reaction conditions.
F Turon et al.
Lipids, 37(8), 817-821 (2002-10-10)
An analytical procedure was developed for regiodistribution analysis of TAG using alpha-MAG prepared by an ethyl magnesium bromide deacylation. In the present communication, the deacylation procedure is shown to lead to representative alpha-MAG, allowing the composition of the native TAG
R G Xie et al.
Steroids, 55(11), 488-490 (1990-11-01)
The reaction of ethyl magnesium bromide and 17 alpha-ethynylestradiol with formaldehyde in the presence of triethyl phosphate or hexamethylphosphoramide gave the 2- and 4-formyl-17 alpha-ethynylestradiol in high yield. Treatment of the formyl derivatives with an alkaline solution of hydrogen peroxide

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