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75666

Sigma-Aldrich

5-(Benzylthio)-1H-tetrazole

≥99.0% (HPLC)

Synonym(s):

5-Benzylmercapto-1,2,3,4-tetrazole, 5-Benzylmercaptotetrazole, 5-Benzylthio-1H-tetrazole, 5-[(Phenylmethyl)thio]-2H-tetrazole

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5 G
$229.00

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About This Item

Empirical Formula (Hill Notation):
C8H8N4S
CAS Number:
Molecular Weight:
192.24
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

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Quality Level

assay

≥99.0% (HPLC)

form

crystals

mp

135-138 °C (DSC-onset)

functional group

phenyl
thioether

SMILES string

C(Sc1nnn[nH]1)c2ccccc2

InChI

1S/C8H8N4S/c1-2-4-7(5-3-1)6-13-8-9-11-12-10-8/h1-5H,6H2,(H,9,10,11,12)

InChI key

GXGKKIPUFAHZIZ-UHFFFAOYSA-N

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1 of 4

This Item
493805L033000554030
assay

≥99.0% (HPLC)

assay

95%

assay

-

assay

99.0%

Quality Level

100

Quality Level

200

Quality Level

200

Quality Level

200

form

crystals

form

-

form

-

form

-

mp

135-138 °C (DSC-onset)

mp

84-90 °C (lit.)

mp

-

mp

168-175 °C (lit.)

functional group

phenyl

functional group

thioether

functional group

-

functional group

nitrile

General description

5-(Benzylthio)-1H-tetrazole (BTT activator) is an organic compound that is used as an activator in the synthesis of oligonucleotides. The activator reacts with the phosphoramidite group to form a highly reactive intermediate. The intermediate then forms an internucleotide bond with the detritylated 5′-hydroxyl group of the growing oligonucleotide chain.

Other Notes

Activator for DNA synthesis; superior alternative to tetrazole[1]

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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S. Pitsch et al.
Helvetica Chimica Acta, 84, 3773-3773 (2001)

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