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759406

Triethylene glycol dimethacrylate

99%, cross-linking reagent polymerization reactions, 200 ppm monomethyl ether hydroquinone as inhibitor

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About This Item

Linear Formula:
CH2=C(CH3)COO(CH2CH2O)3COC(CH3)=CH2
CAS Number:
109-16-0
Molecular Weight:
286.32
NACRES:
NA.23
PubChem Substance ID:
329766782
UNSPSC Code:
12162002
EC Number:
203-652-6
MDL number:
MFCD00008591
Beilstein/REAXYS Number:
1797351

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Product Name

Triethylene glycol dimethacrylate, contains 200 ppm monomethyl ether hydroquinone as inhibitor, 99%

SMILES string

CC(=C)C(=O)OCCOCCOCCOC(=O)C(C)=C

InChI key

HWSSEYVMGDIFMH-UHFFFAOYSA-N

InChI

1S/C14H22O6/c1-11(2)13(15)19-9-7-17-5-6-18-8-10-20-14(16)12(3)4/h1,3,5-10H2,2,4H3

assay

99%

form

liquid

contains

200 ppm monomethyl ether hydroquinone as inhibitor

reaction suitability

reagent type: cross-linking reagent
reaction type: Polymerization Reactions

refractive index

n20/D 1.461 (lit.)
n/D 1.4613

bp

170-172 °C/5 mmHg (lit.)

density

1.092 g/mL at 25 °C (lit.)
1.074 g/mL

polymer architecture

shape: linear
functionality: homobifunctional

storage temp.

2-8°C

Quality Level

100

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This Item
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Triethylene glycol dimethacrylate contains 200 ppm monomethyl ether hydroquinone as inhibitor, 99%

Sigma-Aldrich

759406

Triethylene glycol dimethacrylate

Triethylene glycol dimethacrylate contains 80-120 ppm MEHQ as inhibitor, 95%

Sigma-Aldrich

261548

Triethylene glycol dimethacrylate

Tri(ethyleneglycol) diacrylate contains ≤1000 ppm MEHQ as inhibitor, 97%

Sigma-Aldrich

763977

Tri(ethyleneglycol) diacrylate

Poly(ethylene glycol) dimethacrylate average Mn 550, contains 80-120 ppm MEHQ as inhibitor, 270-330 ppm BHT as inhibitor

Sigma-Aldrich

409510

Poly(ethylene glycol) dimethacrylate

polymer architecture

shape: linear
functionality: homobifunctional

polymer architecture

shape: linear
functionality: homobifunctional

polymer architecture

shape: linear
functionality: homobifunctional

polymer architecture

shape: linear
functionality: homobifunctional

form

liquid

form

liquid

form

liquid

form

liquid

assay

99%

assay

95%

assay

97%

assay

-

Quality Level

100

Quality Level

200

Quality Level

100

Quality Level

200

reaction suitability

reagent type: cross-linking reagent
reaction type: Polymerization Reactions

reaction suitability

reagent type: cross-linking reagent
reaction type: Polymerization Reactions

reaction suitability

reagent type: cross-linking reagent
reaction type: Polymerization Reactions

reaction suitability

reagent type: cross-linking reagent
reaction type: Polymerization Reactions

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

2-8°C

Application

  • Used as a diluent comonomer in dimethacrylate based dental composites.[1]
  • Used as a branching agent in the atom transfer radical polymerization (ATRP) of styrene.[2]

Features and Benefits

Lower viscosity compared to other dimethacrylate monomers enabling higher amounts of filler to be incorporated in dental composites. Non-toxic and can be rapidly polymerized in the presence of oxygen and water. [1]

General description

Triethylene glycol dimethacrylate is used as a cross-linking agent in the synthesis of poly (methacrylic acid-g-ethylene glycol ) hydrogels which shows large changes in swelling due to changes in pH, temperature and solvent composition. [3] They are also used as a divinylic methacrylic monomer which are widely used to form copolymers with divinylbenzene (DVB) and glycidyl methacrylate (GMA) or hydroxyethyl methacrylate (HEMA) comonomers.[4]

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H317

Hazard Classifications

Skin Sens. 1

Storage Class

10 - Combustible liquids

wgk

WGK 1

flash_point_f

332.6 °F - closed cup

flash_point_c

167 °C - closed cup

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Certificates of Analysis (COA)

Lot/Batch Number
0000234211
0000224127
0000234211
0000224127
0000161465

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I Sideridou et al.
Biomaterials, 23(8), 1819-1829 (2002-04-13)
In this work the room-temperature photopolymerization of Bis-GMA, Bis-EMA, urethane dimethacrylate (UDMA) and triethylene glycol dimethacrylate (TEGDMA) induced by camphoroquinone/N,N-dimethylaminoethyl methacrylate, as photo-initiator system, was followed by FT-IR. The results obtained were then fitted by a non-linear least square method
Mono-or narrow disperse poly (methacrylate-co-divinylbenzene) microspheres by precipitation polymerization
Li, W. H., & Stover, H. D.
Journal of Polymer Science Part A: Polymer Chemistry, 37(15), 2899-2907 (1999)
Development of branching in atom transfer radical copolymerization of styrene with triethylene glycol dimethacrylate
Yang, H. J., Jiang, B. B., Huang, W. Y., Zhang, D. L., Kong, L. Z., Chen, J. H., & Yang, Y.
Macromolecules, 42(16), 5976-5982 (2009)
Controlled release by using poly (methacrylic acid-g-ethylene glycol) hydrogels
Peppas, N. A., & Klier, J.
Journal of Controlled Release : Official Journal of the Controlled Release Society, 16(1), 203-214 (1991)
Geum-Jun Han et al.
The journal of adhesive dentistry, 14(5), 461-469 (2012-06-23)
To evaluate the effect of applied power on dental ceramic bonding of composite resin using nonthermal atmospheric pressure plasma (APP). A pencil-type APP torch was used to modify the surface chemical composition and hydrophilicity of dental ceramic and to improve
View All Related Papers

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