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763039
XantPhos Pd G3
95%, solid
Synonym(s):
[(4,5-Bis(diphenylphosphino)-9,9-dimethylxanthene)-2-(2′-amino-1,1′-biphenyl)]palladium(II) methanesulfonate
Select a Size
| Pack Size | SKU | Availability | Price |
|---|---|---|---|
| 250 mg | Available to ship TODAYfromMILWAUKEE | $63.10 $47.32 | |
| 1 g | Available to ship TODAYfromMILWAUKEE | $188.00 | |
| 5 g | Available to ship TODAYfromMILWAUKEE | $775.00 |
About This Item
$47.32
List Price$63.10Save 25%Available to ship TODAYDetails
Product Name
XantPhos Pd G3, 95%
Quality Level
product line
Buchwald precatalyst Generation 3
assay
95%
form
solid
feature
generation 3
reaction suitability
core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst
reaction type: Cross Couplings
mp
164-167 °C (decomposition)
functional group
phosphine
SMILES string
CS(=O)(=O)O[Pd]c1ccccc1-c2ccccc2N.CC3(C)c4cccc(P(c5ccccc5)c6ccccc6)c4Oc7c(cccc37)P(c8ccccc8)c9ccccc9
InChI
1S/C39H32OP2.C12H10N.CH4O3S.Pd/c1-39(2)33-25-15-27-35(41(29-17-7-3-8-18-29)30-19-9-4-10-20-30)37(33)40-38-34(39)26-16-28-36(38)42(31-21-11-5-12-22-31)32-23-13-6-14-24-32;13-12-9-5-4-8-11(12)10-6-2-1-3-7-10;1-5(2,3)4;/h3-28H,1-2H3;1-6,8-9H,13H2;1H3,(H,2,3,4);/q;;;+1/p-1
InChI key
AJVXPGQYAKUTGX-UHFFFAOYSA-M
General description
Application
- Negishi cross-coupling reaction during the synthesis of palmerolides.
- Aminocarbonylation of heteroaryl bromides with carbon monoxide (CO) in the presence of triethylamine.
- Coupling between polyglycosyl thiols and aglycon halides by C-S bond formation.
1 of 1
This Item | |||
|---|---|---|---|
| assay 95% | assay - | assay 98% | assay 98% |
| reaction suitability core: palladium, reaction type: Heck Reaction, reaction type: Negishi Coupling, reaction type: Stille Coupling, reagent type: catalyst | reaction suitability - | reaction suitability core: palladium, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst | reaction suitability - |
| functional group phosphine | functional group - | functional group phosphine | functional group phosphine |
| form solid | form solid | form solid | form solid |
| Quality Level 100 | Quality Level 100 | Quality Level 100 | Quality Level 100 |
| mp 164-167 °C (decomposition) | mp - | mp 146-151 °C (decomposition) | mp 130-140 °C |
Storage Class
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Articles
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G3 and G4 Buchwald palladium precatalysts are the newest air, moisture, and thermally stable crossing-coupling complexes used in bond formation for their versatility and high reactivity.
Related Content
All contents in the foil bag are weighed, plated, packed, and sealed in a glove box under nitrogen.
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 763039-1G | 04061832922737 |
| 763039-250MG | 04061832970806 |
| 763039-5G | 04061832970813 |
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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