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767654

cis-Dichlorobis(dimethyl sulfoxide)platinum(II)

97%, solid

Synonym(s):

cis-Dichlorobis(dimethylsulfoxido)platinum(II), Pt(DMSO)2Cl2

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About This Item

Empirical Formula (Hill Notation):
C4H12Cl2O2PtS2
CAS Number:
22840-91-1
Molecular Weight:
422.25
UNSPSC Code:
12161600
PubChem Substance ID:
329767328
NACRES:
NA.22
MDL number:
MFCD00061452

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Product Name

cis-Dichlorobis(dimethyl sulfoxide)platinum(II), 97%

SMILES string

Cl[Pt]Cl.CS(C)=O.CS(C)=O

InChI

1S/2C2H6OS.2ClH.Pt/c2*1-4(2)3;;;/h2*1-2H3;2*1H;/q;;;;+2/p-2

InChI key

KDADQDWVKZJTDQ-UHFFFAOYSA-L

assay

97%

form

solid

reaction suitability

core: platinum
reagent type: catalyst

mp

218-224 °C

Quality Level

100

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cis-Dichlorobis(dimethyl sulfoxide)platinum(II) 97%

Sigma-Aldrich

767654

cis-Dichlorobis(dimethyl sulfoxide)platinum(II)

cis-Dichlorobis(triethylphosphine)platinum(II) 98%

Sigma-Aldrich

331406

cis-Dichlorobis(triethylphosphine)platinum(II)

cis-Bis(benzonitrile)dichloroplatinum(II) 98%

Sigma-Aldrich

275816

cis-Bis(benzonitrile)dichloroplatinum(II)

cis-Dichlorobis(triphenylphosphine)platinum(II)

Sigma-Aldrich

244945

cis-Dichlorobis(triphenylphosphine)platinum(II)

assay

97%

assay

98%

assay

98%

assay

-

reaction suitability

core: platinum, reagent type: catalyst

reaction suitability

core: platinum, reagent type: catalyst

reaction suitability

core: platinum, reagent type: catalyst

reaction suitability

core: platinum, reagent type: catalyst

form

solid

form

powder

form

-

form

-

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

mp

218-224 °C

mp

193-194 °C (lit.)

mp

224 °C (dec.) (lit.)

mp

≥300 °C (lit.)

Application

cis-Dichlorobis(dimethyl sulfoxide)platinum(II) can be used as a:
  • Catalyst in the oleum-mediated (SO3-H2SO4) methane oxidation to form methyl bisulfate (MBS). [1]
  • Precursor in the synthesis of cyclometalated complexes. [2]

General description

cis-Dichlorobis(dimethyl sulfoxide)platinum(II) is a platinum complex used as a catalyst in various chemical reactions, including the methylation of polyfluorinated aryl imines and methane oxidation. It is identified as an effective C-F activation precatalyst. [1] [3]

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
SHBP4201
SHBM4371
SHBL3138
SHBH0663V
SHBC6199

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R Gorodetsky et al.
Medical physics, 20(4), 1007-1012 (1993-07-01)
Noninvasive analysis of heavy elements in external tissues by diagnostic-x-ray spectrometry (DXS) is presented. Pt can be detected accurately with sensitivity below 1 microgram/g wet weight of tissue. In the present paper the possibility to monitor Pt accumulation and clearance
K R Grigorian et al.
Biofizika, 56(1), 31-34 (2011-03-30)
The interaction of cis-[PtCl2(Me2SO)2] with human serum albumin (HSA) and the sensitivity of the complex towards the thermal denaturation depending on the duration of incubation have been studied by absorption and fluorescence spectroscopy methods. Optimum conditions for cis-[PtCl2(Me2SO)2] binding to
B A Teicher et al.
Cancer chemotherapy and pharmacology, 32(4), 315-319 (1993-01-01)
The survival of bone-marrow granulocyte-macrophage colony-forming units (CFU-GM), an alkylating-agent-sensitive normal tissue, was assessed in mice bearing the EMT-6 parental tumor or the in vivo resistant EMT-6/CDDP, EMT-6/CTX, EMT-6/Thio, and EMT-6/Carbo tumors. The survival pattern of the bone-marrow CFU-GM recapitulated
K Nishio et al.
International journal of cancer, 55(4), 616-622 (1993-10-21)
cis-Diamminedichloroplatinum(II) (CDDP) induced G2-phase arrest in PC-9 human cancer cells. To elucidate how CDDP acts on cell-cycle regulation, we analyzed the effect of CDDP on cell-cycle regulators such as p34cdc2 protein kinase. p34cdc2 protein kinase activity was maximum in G2
Treatment of pathological stage T3N+M0 bladder cancer: the case for observation.
D A Corral et al.
Seminars in urology, 11(2), 64-68 (1993-05-01)
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