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MilliporeSigma

772410

Sigma-Aldrich

PTB7

greener alternative

average Mw 80,000-200,000, PDI ≤3.0

Synonym(s):

Poly({4,8-bis[(2-ethylhexyl)oxy]benzo[1,2-b:4,5-b′]dithiophene-2,6-diyl}{3-fluoro-2-[(2-ethylhexyl)carbonyl]thieno[3,4-b]thiophenediyl})

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100 MG
$738.00

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100 MG
$738.00

About This Item

Empirical Formula (Hill Notation):
(C41H53FO4S4)n
CAS Number:
UNSPSC Code:
12352103
NACRES:
NA.23

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$738.00


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description

Band gap: 1.84 eV

form

solid

mol wt

average Mw 80,000-200,000

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

solubility

chlorobenzene: soluble
chloroform: soluble
dichlorobenzene: soluble

λmax

680 nm (thin film)

orbital energy

HOMO -5.15 eV 
LUMO -3.31 eV 

Mw/Mn

2.4 +/- 0.6

PDI

≤3.0

greener alternative category

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This Item
754005794333901099
PTB7 average Mw 80,000-200,000, PDI ≤3.0

772410

PTB7

PCPDTBT average Mw 7,000-20,000

754005

PCPDTBT

PTB7-Th

794333

PTB7-Th

PBDB-T

901099

PBDB-T

form

solid

form

solid

form

solid

form

powder

description

Band gap: 1.84 eV

description

Band gap: 1.75 eV

description

Band gap: 1.57 eV, Shiny, purple, fiber-like solid

description

Band gap: 1.8 eV, Limited solubility in CHCl3

mol wt

average Mw 80,000-200,000

mol wt

average Mw 7,000-20,000

mol wt

>145,000

mol wt

Mw >50,000 by GPC (GPC standard: PS)

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

-

greener alternative product characteristics

-

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

sustainability

-

sustainability

-

sustainability

Greener Alternative Product

solubility

chlorobenzene: soluble

solubility

-

solubility

chlorobenzene: soluble, dichlorobenzene: soluble

solubility

chlorobenzene: soluble, dichlorobenzene: soluble

General description

PTB7 is a semiconducting polymer used in organic photovoltaics with an energy efficiency of 9.15%. It can act as an electron donor with narrow optical band gaps and excellent π-π conjugation while forming a nanocomposite with fullerenes.[1][2]
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product belongs to Enabling category of greener alternatives thus aligns with "Design for energy efficency". Hole transport organic materials allow perfect energy level alignment with the absorber layer and therefore efficient charge collection, are prone to degradation in ambient conditions.Click here for more information.

Application

High-Efficiency Organic Solar Cells (OPVs)
OPV Device Structure: ITO/PEDOT:PSS/PTB7 :PC71BM/Ca/Al
  • JSC = 14.9 mA/cm2
  • VOC = 0.75 V
  • FF = 0.69
  • PCE = 7.4%
It is majorly used as an active layer that enhances the overall performance by increasing the light absorption and improving the electron mobility of polymeric solar cells (PSCs).[3][4][5][6]

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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