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774138

Sigma-Aldrich

Lithium difluoro(oxalato)borate

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Synonym(s):

LIDFOB, LIF2OB, LIFOB, LIODFB, Lithium difluoro(ethanedioato)borate, Lithium oxalatodigluoroborate

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About This Item

Linear Formula:
LiBF2(C2O4)
CAS Number:
Molecular Weight:
143.77
MDL number:
UNSPSC Code:
26111700
PubChem Substance ID:
NACRES:
NA.23

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form

powder

Quality Level

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Design for Energy Efficiency
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mp

265-271 °C

application(s)

battery manufacturing

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SMILES string

F[B-]1(OC(C(O1)=O)=O)F.[Li+]

InChI

1S/C2BF2O4.Li/c4-3(5)8-1(6)2(7)9-3;/q-1;+1

InChI key

MEDDCIKGDMDORY-UHFFFAOYSA-N

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This Item
757136451622481548
application(s)

battery manufacturing

application(s)

battery manufacturing

application(s)

battery manufacturing

application(s)

battery manufacturing

Quality Level

100

Quality Level

100

Quality Level

200

Quality Level

100

mp

265-271 °C

mp

>300 °C (lit.)

mp

293-300 °C (dec.) (lit.)

mp

>300 °C (lit.)

form

powder

form

powder or crystals

form

powder

form

powder

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

sustainability

Greener Alternative Product

sustainability

Greener Alternative Product

sustainability

Greener Alternative Product

General description

Lithium difluoro(oxalato)borate (LIODFB) is a class of electrolytic materials that can be used in the fabrication of lithium-ion batteries. Lithium-ion batteries consist of anode, cathode, and electrolyte with a charge-discharge cycle. These materials enable the formation of greener and sustainable batteries for electrical energy storage.[1][2][3][4]
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Lithium difluorooxalatoborate (LIODFB) is a salt for high-performance Li-ion batteries with improved cycle life; power capability; low temperature and high rate performance of the battery. It has the advantages of both lithium bis(oxalato)borate (LiBOB) and LiBF4. LIODFB also stabilizes the solid electrolyte interface (SEI) on the surface of a graphite anode and is also used as an additive to improve the cycling efficiency and capacity retention of cells
Our battery grade lithium difluorooxalatoborate (LiODFB) is a thermally stable salt and an electrolytic additive for lithium-ion batteries. LIODFB facilitates the formation of stable solid electrolyte interphase (SEI) on the negative electrode, which enhances the cycling efficiency and safety of the battery. Moreover, LiODFB is capable of stabilizing the solid electrolyte interface (SEI) on the surface of lithium metal, graphite, and silicon anode materials, substantially enhances the cyclic performance, capacity and power retention of the electrochemical cells.[5][6][7] In particular, LiODFB is suitable for high-performance Li-ion batteries operating at low temperatures and fast charge and discharge rates.

Features and Benefits

LiODFB improves the efficiency and safety of lithium-ion batteries, allowing them to deliver better performance over a longer time.
✔ Increases battery life
✔ Stabilizes SEI layer
✔ Suitable for fast charging and low temperatures

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Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


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Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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