All Photos(1)

794171

Sigma-Aldrich

9-Mesityl-10-methylacridinium tetrafluoroborate

Synonym(s):
10-Methyl-9-(2,4,6-trimethylphenyl)acridinium tetrafluoroborate, 9-Mesityl-10-methylacridinium tetrafluoroborate
Empirical Formula (Hill Notation):
C23H22BF4N
CAS Number:
Molecular Weight:
399.23
PubChem Substance ID:
NACRES:
NA.22

reaction suitability

core: acridinium
reagent type: catalyst

Quality Level

photocatalyst activation

450 nm

SMILES string

CC(C=C1C)=CC(C)=C1C2=C3C(C=CC=C3)=[N+](C)C4=CC=CC=C42.F[B-](F)(F)F

InChI

1S/C23H22N.BF4/c1-15-13-16(2)22(17(3)14-15)23-18-9-5-7-11-20(18)24(4)21-12-8-6-10-19(21)23;2-1(3,4)5/h5-14H,1-4H3;/q+1;-1

InChI key

KKMWMXQQOIIJIZ-UHFFFAOYSA-N

Related Categories

Application

Catalyst has been reported by Nicewicz and coworkers to mediate myriad transformations through Photoredox Catalysis. The following applications include the anti-Markovnikov hydroamination of alkenes and addition of carboxylic acids to alkenes and the hydrotrifluoromethylation of styrenes using the Langlois reagent (Aldrich 743232).

Packaging

1 g in glass bottle
250 mg in glass bottle

Precautionary Statements

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis

Certificate of Origin

Articles

Nicewicz Photoredox Catalysts for Anti-Markovnikov Alkene Hydrofunctionalization

While Markovnikov alkene reactivity is very well developed and utilized commonly in the synthesis of commodity and research chemicals, catalytic access to the anti-Markovnikov-selective adducts is a much less-developed endeavor.

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