794171

Sigma-Aldrich

9-Mesityl-10-methylacridinium tetrafluoroborate

Synonym(s):
10-Methyl-9-(2,4,6-trimethylphenyl)acridinium tetrafluoroborate, 9-Mesityl-10-methylacridinium tetrafluoroborate
Empirical Formula (Hill Notation):
C23H22BF4N
CAS Number:
Molecular Weight:
399.23
PubChem Substance ID:
NACRES:
NA.22

reaction suitability

core: acridinium
reagent type: catalyst

Quality Level

photocatalyst activation

450 nm

SMILES string

CC(C=C1C)=CC(C)=C1C2=C3C(C=CC=C3)=[N+](C)C4=CC=CC=C42.F[B-](F)(F)F

InChI

1S/C23H22N.BF4/c1-15-13-16(2)22(17(3)14-15)23-18-9-5-7-11-20(18)24(4)21-12-8-6-10-19(21)23;2-1(3,4)5/h5-14H,1-4H3;/q+1;-1

InChI key

KKMWMXQQOIIJIZ-UHFFFAOYSA-N

Related Categories

Application

Catalyst has been reported by Nicewicz and coworkers to mediate myriad transformations through Photoredox Catalysis. The following applications include the anti-Markovnikov hydroamination of alkenes and addition of carboxylic acids to alkenes and the hydrotrifluoromethylation of styrenes using the Langlois reagent (Aldrich 743232).

Packaging

1 g in glass bottle
250 mg in glass bottle

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Precautionary Statements

hazcat

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

storage_class_code

11 - Combustible Solids

WGK Germany

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis

Certificate of Origin

Articles
While Markovnikov alkene reactivity is very well developed and utilized commonly in the synthesis of commodity and research chemicals, catalytic access to the anti-Markovnikov-selective adducts is a much less-developed endeavor.
Read More

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service