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796557

Stahl Aerobic Oxidation ABNO solution

0.04M ABNO in Acetonitrile, Solution for Oxidation of Primary and Secondary Alcohols

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25 mL

Available to ship TODAYfromMILWAUKEE

$225.00

About This Item

NACRES:
NA.22
UNSPSC Code:
12352000

$225.00

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Quality Level

100

description

Freezing Point: 44.6°F

form

liquid

reaction suitability

reagent type: oxidant

refractive index

n/D 1.357

density

0.796 at 25 °C

storage temp.

2-8°C

General description

Stahl Aerobic Oxidation ABNO solution contains 1-methylimidazole (NMI), 2,2′-bipyridyl (bpy), and ABNO for the oxidation of primary and secondary alcohols.

Application

This convenience solution can be used in tandem with tetrakisacetonitrile copper(I) triflate (685038) for the oxidation of primary alcohols through aerobic conditions developed by the Stahl Research Group.

Other Notes

Technology Spotlight:
Aerobic Alcohol Oxidation Solutions

Stable TEMPO and ABNO Catalyst Solutions for User-Friendly (bpy)Cu/Nitroxyl- Catalyzed Aerobic Alcohol Oxidation

Practical Aerobic Alcohol Oxidation with Cu/Nitroxyl and Nitroxyl/NOx Catalyst Systems

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This Item
796549763284TC-1L-BK
Stahl Aerobic Oxidation ABNO solution 0.04M ABNO in Acetonitrile, Solution for Oxidation of Primary and Secondary Alcohols

Sigma-Aldrich

796557

Stahl Aerobic Oxidation ABNO solution

Stahl Aerobic Oxidation TEMPO solution 0.2 M in acetonitrile, Solution for Oxidation of Primary Alcohols

Sigma-Aldrich

796549

Stahl Aerobic Oxidation TEMPO solution

9-Azabicyclo[3.3.1]nonane N-oxyl 95%

Sigma-Aldrich

763284

9-Azabicyclo[3.3.1]nonane N-oxyl

Millipore

Millipore

TC-1L-BK

Blood typing Bulk Reagent Diluents - ABO & RHD (Rh) Specificities

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

2-8°C

storage temp.

2-8°C

reaction suitability

reagent type: oxidant

reaction suitability

reagent type: oxidant

reaction suitability

reagent type: ligand

reaction suitability

-

density

0.796 at 25 °C

density

-

density

-

density

-

description

Freezing Point: 44.6°F

description

-

description

-

description

-

Quality Level

100

Quality Level

100

Quality Level

200

Quality Level

600

refractive index

n/D 1.357

refractive index

-

refractive index

-

refractive index

-

signalword

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2

Storage Class

3 - Flammable liquids

wgk

WGK 3

flash_point_f

43.5 °F

flash_point_c

6.38 °C

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Certificates of Analysis (COA)

Lot/Batch Number
MKCN0911
MKBV0532V

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Articles

Aerobic Alcohol Oxidation Solutions

Alcohol oxidation yields aldehydes and ketones, crucial intermediates in organic synthesis.

Related Content

Stahl Group – Professor Product Portal

he Stahl Lab focuses on the development of catalysts and catalytic reactions for selective oxidation of organic molecules, with particular emphasis on aerobic oxidation reactions.

Efficient Aerobic Oxidation of Secondary Alcohols at Ambient Temperature with an ABNO/NOx Catalyst System
Lauber, MB, and Stahl, SS.
ACS Catalysis, 3 (11), 2612?2616-2612?2616 (2013)
Janelle E Steves et al.
The Journal of organic chemistry, 80(21), 11184-11188 (2015-10-13)
Two solutions, one consisting of bpy/TEMPO/NMI and the other bpy/ABNO/NMI (bpy =2,2'-bipyridyl; TEMPO = 2,2,6,6-tetramethylpiperidine N-oxyl, ABNO = 9-azabicyclo[3.3.1]nonane N-oxyl; NMI = N-methylimidazole), in acetonitrile are shown to have good long-term stability (≥1 year) under air at 5 °C. The
Janelle E Steves et al.
Journal of the American Chemical Society, 135(42), 15742-15745 (2013-10-17)
Cu/TEMPO catalyst systems promote efficient aerobic oxidation of sterically unhindered primary alcohols and electronically activated substrates, but they show reduced reactivity with aliphatic and secondary alcohols. Here, we report a catalyst system, consisting of ((MeO)bpy)Cu(I)(OTf) and ABNO ((MeO)bpy = 4,4'-dimethoxy-2,2'-bipyridine;

Global Trade Item Number

SKUGTIN
796557-25ML04061838103277

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