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802948

Sigma-Aldrich

(dppf)Ni(o-tolyl)Cl

95%, powder

Synonym(s):

Buchwald Ni Catalyst

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250 MG
$134.00
1 G
$405.00

About This Item

Empirical Formula (Hill Notation):
C41H35ClFeNiP2
CAS Number:
1501945-23-8
Molecular Weight:
739.66
MDL number:
MFCD28411349
UNSPSC Code:
12161600
PubChem Substance ID:
329768766
NACRES:
NA.22

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$134.00

In StockDetails

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Product Name

(dppf)Ni(o-tolyl)Cl,

assay

95%

Quality Level

100

form

powder

reaction suitability

core: nickel
reaction type: Cross Couplings
reagent type: catalyst

mp

173 °C

storage temp.

2-8°C

SMILES string

CC1=CC=CC=C1[Ni]Cl.[C]2(P(C3=CC=CC=C3)C4=CC=CC=C4)[C][C][C][C]2.[C]5(P(C6=CC=CC=C6)C7=CC=CC=C7)[C][C][C][C]5.[Fe]

InChI

1S/2C17H14P.C7H7.ClH.Fe.Ni/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;1-7-5-3-2-4-6-7;;;/h2*1-14H;2-5H,1H3;1H;;/q;;;;;+1/p-1

InChI key

LGLPATFHWYLMCO-UHFFFAOYSA-M

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This Item
804398905070919578
(dppf)Ni(o-tolyl)Cl

802948

(dppf)Ni(o-tolyl)Cl

[(TMEDA)Ni(o-tolyl)Cl] 95%

804398

[(TMEDA)Ni(o-tolyl)Cl]

[(TEEDA)Ni(o-tolyl)Cl] ≥95%

905070

[(TEEDA)Ni(o-tolyl)Cl]

PAd2-DalPhos Ni(o-tolyl)Cl

919578

PAd2-DalPhos Ni(o-tolyl)Cl

reaction suitability

core: nickel, reagent type: catalyst, reaction type: Cross Couplings

reaction suitability

core: nickel, reaction type: Cross Couplings, reagent type: catalyst

reaction suitability

core: nickel, reaction type: Cross Couplings, reagent type: catalyst

reaction suitability

-

assay

95%

assay

95%

assay

≥95%

assay

-

form

powder

form

powder

form

powder or crystals

form

powder

Quality Level

100

Quality Level

100

Quality Level

-

Quality Level

100

storage temp.

2-8°C

storage temp.

-

storage temp.

-

storage temp.

-

mp

173 °C

mp

-

mp

>300 °C

mp

>300 °C

General description

(dppf)Ni(o-tolyl)Cl is an air stable reagent. Its crystal structure has been investigated by X-ray studies. (dppf)Ni(o-tolyl)Cl can be prepared from (Ph3P)2Ni(o-tolyl)Cl. It is widely employed as a precatalyst for various C-N bond formation reactions. Efficacy of (dppf)Ni(o-tolyl)Cl as a precatalyst for the amination of 4-n-butylchlorobenzene with morpholine under various optimized reaction conditions has been investigated.[1]

pictograms

Health hazardEnvironment
GHS08,GHS09

signalword

Danger

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 1 Inhalation

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Questions

  1. Is it water soluble?

    1 answer

    1. This product is not tested for solubility. A literature search does not yield conclusive information regarding water solubility. Further experimentation would be necessary to determine this parameter. Please see the links below to review articles that may be helpful.

      Well-defined nickel and palladium precatalysts for cross-coupling
      https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5637737/

      Exploiting the trifluoroethyl group as a precatalyst ligand in nickel-catalyzed Suzuki-type alkylations
      https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6540912/

      Helpful?

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