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804010

Sigma-Aldrich

Co(salen,t-Bu, t-Bu)Cl

Empirical Formula (Hill Notation):
C36H52ClCoN2O2
Molecular Weight:
639.20
PubChem Substance ID:

form

powder

reaction suitability

reagent type: catalyst
core: cobalt

mp

250 °C

storage temp.

2-8°C

SMILES string

Cl[Co]1OC(C(C(C)(C)C)=CC(C(C)(C)C)=C2)=C2/C=N/[C@](CCCC3)([H])[C@@]3([H])/N=C/C(C=C(C(C)(C)C)C=C4C(C)(C)C)=C4O1

InChI

1S/C36H54N2O2.ClH.Co/c1-33(2,3)25-17-23(31(39)27(19-25)35(7,8)9)21-37-29-15-13-14-16-30(29)38-22-24-18-26(34(4,5)6)20-28(32(24)40)36(10,11)12;;/h17-22,29-30,39-40H,13-16H2,1-12H3;1H;/q;;+3/p-3/b37-21+,38-22+;;/t29-,30-;;/m0../s1

InChI key

DIPYCKRNYQWVPM-RUIQGICGSA-K

Application

When utilized with organosilanes, catalytic amounts of Co(salen,t-Bu, t-Bu)Cl effects the isomerization of terminal alkenes.

Packaging

500 mg in glass bottle

Certificate of Analysis

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Certificate of Origin

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More Documents

Quotes and Ordering

Related Content

Simplified Olefin Isomerization by Cobalt/Silane

Recently, the Shenvi lab has repurposed Jacobsen’s cobalt chloride complex, Co(salen,t-Bu, t-Bu)Cl, to enable positional isomerization of terminal alkenes using reversible hydrogen atom transfer (HAT).

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