Documents
80631
Sodium bis(trimethylsilyl)amide solution
40% in THF
Recommended Products
form
liquid
concentration
40% in THF
SMILES string
C[Si](C)(C)N([Na])[Si](C)(C)C
InChI
1S/C6H18NSi2.Na/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1
InChI key
WRIKHQLVHPKCJU-UHFFFAOYSA-N
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Related Categories
1 of 4
This Item | 702722 | 277304 | 245585 |
|---|---|---|---|
| concentration 40% in THF | concentration 1 M in THF | concentration 0.5 M in toluene | concentration 1.0 M in THF |
| Quality Level 200 | Quality Level 200 | Quality Level 200 | Quality Level 200 |
Application
- Sodium bis(trimethylsilyl)amide, also known as NaHMDS, is a metal dialkylamide reagent that combines both high basicity and nucleophilicity. It is a general reagent used for the enolization of carbonyl compounds.
- It can be used to prepare phosphonium ylides in Wittig reaction.
- NaHMDS solution can also be used as a source of nitrogen in aminomethylation and in the synthesis of primary amines from the corresponding alkyl halides.
Other Notes
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
Supplementary Hazards
Storage Class Code
3 - Flammable liquids
WGK
WGK 2
Flash Point(F)
1.4 °F - closed cup
Flash Point(C)
-17 °C - closed cup
Personal Protective Equipment
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