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87651

Sigma-Aldrich

Tetrakis[tris(dimethylamino)phosphoranylidenamino]phosphonium chloride

95%

Synonym(s):
Phosphazenium chloride
Linear Formula:
[[(CH3)2N]3P=N]4PCl
CAS Number:
Molecular Weight:
775.26
MDL number:
PubChem Substance ID:
NACRES:
NA.22

assay

95%

mp

251 °C (dec.) (lit.)

storage temp.

2-8°C

SMILES string

[Cl-].CN(C)P(=N[P+](N=P(N(C)C)(N(C)C)N(C)C)(N=P(N(C)C)(N(C)C)N(C)C)N=P(N(C)C)(N(C)C)N(C)C)(N(C)C)N(C)C

InChI

1S/C24H72N16P5.ClH/c1-29(2)42(30(3)4,31(5)6)25-41(26-43(32(7)8,33(9)10)34(11)12,27-44(35(13)14,36(15)16)37(17)18)28-45(38(19)20,39(21)22)40(23)24;/h1-24H3;1H/q+1;/p-1

InChI key

NYTYWTQXLWNFFQ-UHFFFAOYSA-M

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Application

Tetrakis[tris(dimethylamino)phosphoranylidenamino]phosphonium chloride can be used:
  • As a lipophilic additive in the pH-responsive polymers and solvent-processible polymer membranes.
  • To prepare tetrakis[tris(dimethylamino)phosphoranylidenamino] phosphonium hydroxide, which acts as a basic catalyst for the ring-opening polymerization of siloxanes.

Packaging

1 g in glass bottle

Other Notes

Extremely stable, lipophilic PTC; Selective O-methylation of ketone enolates

Pictograms

Exclamation mark

Signal Word

Warning

Hazard Statements

Precautionary Statements

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificate of Analysis

Certificate of Origin

E.V. Dehmlow et al.
J. Chem. Res. Synop., 224-224 (1989)
Ring-opening polymerization of siloxanes using phosphazene base catalysts
Hupfield PC and Taylor RG
Journal of Inorganic and Organometallic Polymers and Materials, 9(1), 17-34 (1999)
Potentiometric pH response of polymer membranes incorporated with ion-exchangers
Kim MH, et al.
Analytical Sciences, 17(8), 995-997 (2001)
Solvent-processible polymer membrane-based liquid junction-free reference electrode
Lee HJ, et al.
Analytical Chemistry, 70(16), 3377-3383 (1998)
E.V. Dehmlow et al.
Zeitschrift fur Naturforschung, B: Chemical Sciences, 45, 409-409 (1990)

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