Skip to Content
MilliporeSigma

Key Documents

View All Documentation

Skip To

900941

Chloro(4-cyanophenyl)[(R)-1-[(S)-2-[bis(4-fluorophenyl]phosphino]ferrocenyl]ethyldi-tert-butylphosphine]nickel(II)

≥95%, powder or solid

Synonym(s):

SK-J014-1n

Sign In to View Organizational & Contract Pricing.

Select a Size

Change View
Pack SizeSKUAvailabilityPrice
250 mg
Check Cart for Availability
$261.00

About This Item

Empirical Formula (Hill Notation):
C39H42ClF2FeNNiP2
CAS Number:
2049086-37-3
Molecular Weight:
774.69
MDL number:
MFCD31619172
UNSPSC Code:
12352103
NACRES:
NA.22

$261.00

Check Cart for Availability
​
Request a Bulk Order
​
Technical Service
Need help? Our team of experienced scientists is here for you.
Let Us Assist

Product Name

Chloro(4-cyanophenyl)[(R)-1-[(S)-2-[bis(4-fluorophenyl]phosphino]ferrocenyl]ethyldi-tert-butylphosphine]nickel(II), ≥95%

Quality Segment

100

assay

≥95%

form

powder or solid

reaction suitability

core: nickel, reaction type: Cross Couplings, reagent type: catalyst

SMILES string

CC(C)(C)P(C(C)(C)C)C[C]1[C][C][C][C]1P(C2=CC=C(F)C=C2)C3=CC=C(F)C=C3.Cl[Ni]C4=CC=C(C#N)C=C4.[C]5[C][C][C][C]5.[Fe]

Application

Amination of functionalized aryl chlorides with ammonia and ammonium salts.

Compare Similar Items

View Full Comparison

Show Differences

1 of 1

This Item
900942900944900943
Chloro(4-cyanophenyl)[(R)-1-[(S)-2-[bis(4-fluorophenyl]phosphino]ferrocenyl]ethyldi-tert-butylphosphine]nickel(II) ≥95%

Sigma-Aldrich

900941

Chloro(4-cyanophenyl)[(R)-1-[(S)-2-[bis(4-fluorophenyl]phosphino]ferrocenyl]ethyldi-tert-butylphosphine]nickel(II)

Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine]nickel(II) ≥95%

Sigma-Aldrich

900942

Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldiphenylphosphine]nickel(II)

Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylditertbutylphosphine]nickel(II) ≥95%

Sigma-Aldrich

900944

Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylditertbutylphosphine]nickel(II)

Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine]nickel(II)

Sigma-Aldrich

900943

Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine]nickel(II)

assay

≥95%

assay

≥95%

assay

≥95%

assay

-

reaction suitability

core: nickel, reagent type: catalyst, reaction type: Cross Couplings

reaction suitability

core: nickel, reaction type: Cross Couplings, reagent type: catalyst

reaction suitability

core: nickel, reaction type: Cross Couplings, reagent type: catalyst
reaction type: Asymmetric synthesis

reaction suitability

core: nickel, reaction type: Cross Couplings, reagent type: catalyst
reaction type: Asymmetric synthesis

form

powder or solid

form

powder or solid

form

powder or solid

form

powder or solid

Quality Level

100

Quality Level

100

Quality Level

100

Quality Level

100

signalword

Warning

Hazard Classifications

Aquatic Chronic 2 - Repr. 2 - Skin Irrit. 2

Storage Class

4.1B - Flammable solid hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
MKCM9788
MKCF1834

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Evaluating 1, 1?-Bis (phosphino) ferrocene Ancillary Ligand Variants in the Nickel-Catalyzed C?N Cross-Coupling of (Hetero) aryl Chlorides.
Clark J S, et al.
Organometallics, 36(3), 679-686 (2017)
Nickel?Catalyzed Monoarylation of Ammonia.
Borzenko A, et al.
Angewandte Chemie (International Edition in English), 54(12), 3773-3777 (2015)
Nickel?Catalyzed Amination of Aryl Chlorides with Ammonia or Ammonium Salts.
Green R A and Hartwig J F
Angewandte Chemie (International Edition in English), 54(12), 3768-3772 (2015)
View All Related Papers

Global Trade Item Number

SKUGTIN
900941-250MG04061833315286

Questions

Reviews

No rating value

Active Filters