900943

Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine]nickel(II)

powder or solid

• Synonym(s): SK-J003-1n
• Empirical Formula (Hill Notation): C₄₃H₆₀ClFeNNiP₂
• CAS Number: 2049086-35-1
• Molecular Weight: 802.88
• MDL number: MFCD31619174
• UNSPSC Code: 12352103
• NACRES: NA.22

Properties

• Product Name: Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyldicyclohexylphosphine]nickel(II),
• form: powder or solid
• Quality Segment: 100
• reaction suitability: core: nickel, reaction type: Cross Couplings, reagent type: catalyst; reaction type: Asymmetric synthesis
• SMILES string: Cl[Ni+2]C1=CC=C(C#N)C=C1.C[C@@H](P(C2CCCCC2)C3CCCCC3)[C]4[C][C][C][C]4P(C5CCCCC5)C6CCCCC6.[C]7[C][C][C][C]7.[Fe]

Description

Application

Amination of aryl chlorides, bromides and sulfonates with ammonia. Amination of aryl carbamates with ammonia or ammonium salts.

Other Notes

Nickel-Catalyzed Monoarylation of Ammonia
Valorization of the Primary Building Blocks Ammonia and Acetone Featuring Pd- and Ni-Catalyzed Monoarylations

Safety Information

• pictograms: GHS08,GHS07,GHS09
• signalword: Warning
• hcodes: H315,H361d,H411
• pcodes: P202 - P264 - P273 - P280 - P302 + P352 - P308 + P313
• Hazard Classifications: Aquatic Chronic 2 - Repr. 2 - Skin Irrit. 2
• Storage Class: 4.1B - Flammable solid hazardous materials
• wgk: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable