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901409

[Ir(dF(Me)ppy)2(dtbbpy)]PF6

solid

Synonym(s):

Iridium(III) bis[2-(2,4-difluorophenyl)-5-methylpyridine-N,C20]-4,40-di-tert-butyl-2,20-bipyridine hexafluorophosphate

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Pack SizeSKUAvailabilityPrice
100 mg

Available to ship TODAYfromMILWAUKEE

$376.00

About This Item

Empirical Formula (Hill Notation):
C42H40F10IrN4P
CAS Number:
1335047-34-1
Molecular Weight:
1013.97
MDL number:
MFCD31619196
UNSPSC Code:
12161600
NACRES:
NA.22

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Product Name

[Ir(dF(Me)ppy)2(dtbbpy)]PF6,

form

solid

Quality Level

100

reaction suitability

core: iridium, reaction type: Photocatalysis, reagent type: catalyst

photocatalyst activation

450 nm

InChI key

XAJPUJWOMJJPNU-UHFFFAOYSA-N

Application

[Ir(dF(Me)ppy)2(dtbbpy)]PF6 is a photocatalyst readily facilitates hydroamination of olefins as well as the decarboxylative arylation and vinylation of carboxylic acids via metallaphotoredox catalysis.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

Catalytic intermolecular hydroaminations of unactivated olefins with secondary alkyl amines

Merging photoredox and nickel catalysis: Decarboxylative cross-coupling of carboxylic acids with vinyl halides

Enhanced luminescent iridium(III) complexes bearing aryltriazole cyclometallated ligands

Site-Selective and Stereoselective C-H Alkylations of Carbohydrates via Combined Diarylborinic Acid and Photoredox Catalysis

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This Item
747793908568905917
[Ir(dF(Me)ppy)2(dtbbpy)]PF6

Sigma-Aldrich

901409

[Ir(dF(Me)ppy)2(dtbbpy)]PF6

(Ir[dF(CF3)ppy]2(dtbpy))PF6

Sigma-Aldrich

747793

(Ir[dF(CF3)ppy]2(dtbpy))PF6

[Ir(dFCF3ppy)2-(5,5’-dCF3bpy)]PF6 ≥95%

Sigma-Aldrich

908568

[Ir(dFCF3ppy)2-(5,5′-dCF3bpy)]PF6

(Ir[Me(Me)ppy]2(dtbpy))PF6

Sigma-Aldrich

905917

(Ir[Me(Me)ppy]2(dtbpy))PF6

reaction suitability

core: iridium, reagent type: catalyst, reaction type: Photocatalysis

reaction suitability

core: iridium, reagent type: catalyst
reaction type: Photocatalysis

reaction suitability

-

reaction suitability

core: iridium, reagent type: catalyst
reaction type: Photocatalysis

form

solid

form

solid

form

powder or crystals

form

powder

Quality Level

100

Quality Level

100

Quality Level

-

Quality Level

-

photocatalyst activation

450 nm

photocatalyst activation

450 nm

photocatalyst activation

460 nm

photocatalyst activation

465 nm

Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Certificates of Analysis (COA)

Lot/Batch Number
MKCQ2750
MKCJ5323
MKCK6936

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Correlating electronic structures to electrochemiluminescence of cationic Ir complexes.
Swanick KN, et al.
Royal Society of Chemistry Advances, 43, 19961-19964 (2013)
Victoria Dimakos et al.
Journal of the American Chemical Society, 141(13), 5149-5153 (2019-03-23)
Diphenylborinic acid serves as a cocatalyst for site- and stereoselective C-H alkylation reactions of carbohydrates under photoredox conditions using quinuclidine as the hydrogen atom transfer mediator. Products arising from selective abstraction of the equatorial hydrogens of cis-1,2-diol moieties, followed by
Adam Noble et al.
Journal of the American Chemical Society, 137(2), 624-627 (2014-12-19)
Decarboxylative cross-coupling of alkyl carboxylic acids with vinyl halides has been accomplished through the synergistic merger of photoredox and nickel catalysis. This new methodology has been successfully applied to a variety of α-oxy and α-amino acids, as well as simple
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Global Trade Item Number

SKUGTIN
901409-100MG04061835503476

Questions

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  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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