(BPhen)Ni(OAc)₂.xH₂O

Name: (BPhen)Ni(OAc)<SUB>2</SUB>.xH<SUB>2</SUB>O
Brand: ALDRICH
Price: 128 USD

≥95%, powder or crystals

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250 MG

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About This Item

Empirical Formula (Hill Notation):

C₂₈H₂₂N₂NiO₄

CAS Number:

2304339-11-3

Molecular Weight:

509.18

MDL number:

MFCD31807324

UNSPSC Code:

12161600

NACRES:

NA.22

Key Documents

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Product Name

(BPhen)Ni(OAc)₂.xH₂O,

InChI

1S/C24H16N2.2C2H4O2.Ni/c1-3-7-17(8-4-1)19-13-15-25-23-21(19)11-12-22-20(14-16-26-24(22)23)18-9-5-2-6-10-18;2*1-2(3)4;/h1-16H;2*1H3,(H,3,4);/q;;;+2/p-2

InChI key

DONATKZVTHVGHJ-UHFFFAOYSA-L

SMILES string

O=C(O[Ni]OC(C)=O)C.C1(C2=CC=CC=C2)=CC=NC3=C1C=CC4=C3N=CC=C4C5=CC=CC=C5

assay

≥95%

form

powder or crystals

reaction suitability

core: nickel
reaction type: Cross Couplings
reagent type: catalyst

mp

>300 °C

Related Categories

Catalysts

Cross-Coupling Catalysts

Nickel Catalysts

Transition Metal Catalysts

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1 of 4

This Item	903019	902985	900941
Sigma-Aldrich 902993 (BPhen)Ni(OAc)₂.xH₂O	Sigma-Aldrich 903019 [4,4′-Dimethyl-2,2′-bipyridine]nickel(II) dichloride hydrate	Sigma-Aldrich 902985 (Bathocuproine)NiBr₂	Sigma-Aldrich 900941 Chloro(4-cyanophenyl)[(R)-1-[(S)-2-[bis(4-fluorophenyl]phosphino]ferrocenyl]ethyldi-tert-butylphosphine]nickel(II)
reaction suitability core: nickel, reagent type: catalyst, reaction type: Cross Couplings	reaction suitability core: nickel, reaction type: Cross Couplings, reagent type: catalyst	reaction suitability core: nickel, reaction type: Cross Couplings, reagent type: catalyst	reaction suitability core: nickel, reaction type: Cross Couplings, reagent type: catalyst
assay ≥95%	assay ≥95%	assay -	assay ≥95%
form powder or crystals	form powder or crystals	form powder or crystals	form powder or solid
mp >300 °C	mp >300 °C	mp >300 °C	mp -

Application

Catalyst for cross couplings via C-N bond activation

Disclaimer

Store under N₂ atmosphere

Other Notes

Harnessing Alkyl Amines as Electrophiles for Nickel-Catalyzed Cross Couplings via C–N Bond Activation

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Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Harnessing Alkyl Amines as Electrophiles for Nickel-Catalyzed Cross Couplings via C-N Bond Activation.

Corey H Basch et al.

Journal of the American Chemical Society, 139(15), 5313-5316 (2017-04-01)

We developed a strategy to harness alkyl amines as alkylating agents via C-N bond activation. This Suzuki-Miyaura cross coupling of alkylpyridinium salts, readily formed from primary amines, is the first example of a metal-catalyzed cross coupling via C-N bond activation

Articles

Nickel-based Catalysts

Nickel complexes catalyze various synthetic reactions like oxidative addition, C-H activation, and cross-coupling.

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(BPhen)Ni(OAc)2.xH2O