MilliporeSigma
All Photos(2)

903000

Sigma-Aldrich

[4,4′-Bis(1,1-dimethylethyl)-2,2′-bipyridine] nickel (II) dichloride

All Photos(2)
Synonym(s):
(4,4′-dtbbpy)NiCl2
Empirical Formula (Hill Notation):
C18H24Cl2N2Ni
CAS Number:
1034901-50-2
Molecular Weight:
398.00

Recommended Products

Slide 1 of 10

1 of 10

[Ni(dtbbpy)(H2O)4]Cl2

Sigma-Aldrich

917745

[Ni(dtbbpy)(H2O)4]Cl2

4,4′-Di-tert-butyl-2,2′-dipyridyl 98%

Sigma-Aldrich

515477

4,4′-Di-tert-butyl-2,2′-dipyridyl

98%

Nickel(II) bromide ethylene glycol dimethyl ether complex 97%

Sigma-Aldrich

406341

Nickel(II) bromide ethylene glycol dimethyl ether complex

97%

Nickel(II) chloride ethylene glycol dimethyl ether complex 98%

Sigma-Aldrich

696668

Nickel(II) chloride ethylene glycol dimethyl ether complex

98%

(Bathocuproine)NiBr2

Sigma-Aldrich

902985

(Bathocuproine)NiBr2

(Ir[dF(CF3)ppy]2(dtbpy))PF6

Sigma-Aldrich

747793

(Ir[dF(CF3)ppy]2(dtbpy))PF6

(4,4′-dMeObpy)NiCl2

Sigma-Aldrich

911534

(4,4′-dMeObpy)NiCl2

[Ir(dtbbpy)(ppy)2]PF6

Sigma-Aldrich

747769

[Ir(dtbbpy)(ppy)2]PF6

Dibromobis(triphenylphosphine)nickel(II) 99%

Sigma-Aldrich

331708

Dibromobis(triphenylphosphine)nickel(II)

99%

Ni(bpy)3Br2

Sigma-Aldrich

ALD00608

Ni(bpy)3Br2

form

powder or crystals

reaction suitability

core: nickel
reagent type: catalyst

mp

>300 °C

SMILES string

CC(C1=CC(C2=CC(C(C)(C)C)=CC=N2)=NC=C1)(C)C.Cl[Ni]Cl

Related Categories

Application

[4,4′-Bis(1,1-dimethylethyl)-2,2′-bipyridine] nickel (II) dichloride can be used as a catalyst in:
  • Decarboxylative arylation of oxo acids.
  • Acylation of ethers.
  • Cross-coupling of aryl bromides with alcohols.

Packaging

500 mg

Other Notes

Merging Photoredox and Nickel Catalysis: The Direct Synthesis of Ketones by the Decarboxylative Arylation of α-Oxo Acids

Photocatalytic α-Acylation of Ethers

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Certificate of Analysis

Enter Lot Number to search for Certificate of Analysis (COA).

Certificate of Origin

Enter Lot Number to search for Certificate of Origin (COO).

More Documents

Structure Search

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service