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90350

Sigma-Aldrich

Triethylamine hydrochloride

≥99.0% (AT)

Synonym(s):

N,N-Diethylethanamine hydrochloride, Triethylamine monohydrochloride, Triethylammonium chloride

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$181.00

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50 G
$46.50
250 G
$56.60
1 KG
$181.00

About This Item

Linear Formula:
(C2H5)3N · HCl
CAS Number:
Molecular Weight:
137.65
Beilstein/REAXYS Number:
3906409
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

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$46.50


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Quality Level

assay

≥99.0% (AT)

form

crystals

mp

261 °C (dec.) (lit.)

solubility

water: soluble 1 g/10 mL

functional group

amine

SMILES string

Cl.CCN(CC)CC

InChI

1S/C6H15N.ClH/c1-4-7(5-2)6-3;/h4-6H2,1-3H3;1H

InChI key

ILWRPSCZWQJDMK-UHFFFAOYSA-N

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This Item
639612002350070
assay

≥99.0% (AT)

assay

99.0-101.0% (AT)

assay

≥99.0% (AT)

assay

≥99.0% (AT)

solubility

water: soluble 1 g/10 mL

solubility

H2O: 1 g/10 mL, clear, colorless

solubility

H2O: soluble 0.5 g/10 mL

solubility

H2O: 0.1 g/mL, clear, colorless

Quality Level

200

Quality Level

-

Quality Level

200

Quality Level

200

mp

261 °C (dec.) (lit.)

mp

256-259 °C, 261 °C (dec.) (lit.)

mp

~155 °C (dec.)

mp

-

form

crystals

form

solid

form

solid

form

solid

functional group

amine

functional group

-

functional group

-

functional group

amide, amine

General description

Triethylamine hydrochloride can be used as a:
  • Catalyst to synthesize diphenylmethane via Friedel-Crafts reaction of benzene with benzyl chloride.[1]
  • Reactant in the ionic liquid-catalyzed synthesis of quaternary ammonium salts with dialkyl carbonates.[2]
It can also be used as a proton donor:
  • For the titanocene (III)-catalyzed intramolecular ring-opening arylation of epoxides.[3]
  • In intramolecular Kinugasa reaction to synthesize β-lactams.[4][4]

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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