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909181

Sigma-Aldrich

2,7-Dimethyl-9-mesityl-10-methylacridinium tetrafluoroborate

powder

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About This Item

Empirical Formula (Hill Notation):
C25H26BF4N
CAS Number:
1621019-97-3
Molecular Weight:
427.29
MDL number:
MFCD32173817
UNSPSC Code:
12352101
NACRES:
NA.22

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Product Name

2,7-Dimethyl-9-mesityl-10-methylacridinium tetrafluoroborate,

form

powder

reaction suitability

reaction type: Photocatalysis
reagent type: catalyst

SMILES string

[B-](F)(F)(F)F.[n+]1(c2c(c(c4c1ccc(c4)C)c3c(cc(cc3C)C)C)cc(cc2)C)C

InChI key

UCBSHEKJRRAYNP-UHFFFAOYSA-N

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This Item
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2,7-Dimethyl-9-mesityl-10-methylacridinium tetrafluoroborate

Sigma-Aldrich

909181

2,7-Dimethyl-9-mesityl-10-methylacridinium tetrafluoroborate

2,7-Dimethoxy-9-mesityl-10-methylacridinium tetrafluoroborate

Sigma-Aldrich

909327

2,7-Dimethoxy-9-mesityl-10-methylacridinium tetrafluoroborate

2,7-Difluoro-9-mesityl-10-methylacridinium tetrafluoroborate

Sigma-Aldrich

909254

2,7-Difluoro-9-mesityl-10-methylacridinium tetrafluoroborate

2,7-Dibromo-9-mesityl-10-methylacridinium tetrafluoroborate

Sigma-Aldrich

909033

2,7-Dibromo-9-mesityl-10-methylacridinium tetrafluoroborate

reaction suitability

reaction type: Photocatalysis, reagent type: catalyst

reaction suitability

reaction type: Photocatalysis, reagent type: catalyst

reaction suitability

reaction type: Photocatalysis, reagent type: catalyst

reaction suitability

reaction type: Photocatalysis, reagent type: catalyst

form

powder

form

powder

form

powder or crystals

form

powder or crystals

Application

Robust acridinium-based photocatalyst reported by Nicewicz and coworkers as an alternative to transition-metal-based photocatalysts with higher chemical stability and attenuated redox potential.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

The direct anti-Markovnikov addition of mineral acids to styrenes

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

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Dale J Wilger et al.
Nature chemistry, 6(8), 720-726 (2014-07-24)
The direct anti-Markovnikov addition of strong Brønsted acids to alkenes remains an unsolved problem in synthetic chemistry. Here, we report an efficient organic photoredox catalyst system for the addition of HCl, HF and also phosphoric and sulfonic acids to alkenes

Related Content

Nicewicz Group – Prof. Product Portal

Nicewicz lab focuses on reactive cation radical species for selective reactions, advancing synthesis methodologies for various functional groups.

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