913154
1,10-Phenanthroline nickel (ll) dibromide
powder
Synonym(s):
(phen)NiBr2
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1 G
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About This Item
Empirical Formula (Hill Notation):
C12H8Br2N2Ni
CAS Number:
Molecular Weight:
398.71
MDL number:
UNSPSC Code:
12352200
NACRES:
NA.22
Form:
powder
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Product Name
1,10-Phenanthroline nickel (ll) dibromide,
form
powder
Quality Level
reaction suitability
reagent type: catalyst
reaction type: Cross Couplings
SMILES string
Br[Ni]1(Br)[N]2=CC=CC3=C2C([N]1=CC=C4)=C4C=C3
Application
1,10-Phenanthroline nickel (ll) dibromide is a Ni precatalyst used for a variety of cross-coupling reactions, including N-alkylation of amides and arylation of alcohols.
Storage Class
11 - Combustible Solids
wgk
WGK 3
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Jack Twilton et al.
Angewandte Chemie (International ed. in English), 57(19), 5369-5373 (2018-03-01)
The combination of nickel metallaphotoredox catalysis, hydrogen atom transfer catalysis, and a Lewis acid activation mode, has led to the development of an arylation method for the selective functionalization of alcohol α-hydroxy C-H bonds. This approach employs zinc-mediated alcohol deprotonation
Global Trade Item Number
| SKU | GTIN |
|---|---|
| 913154-5G | 04061841784296 |
| 913154-1G | 04061841784289 |
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