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Sigma-Aldrich

Al-doped lithium lanthanum zirconium oxide (LLZO)

solid electrolyte, powder, battery grade

Synonym(s):

Aluminum-doped cubic garnet LLZO, LLZALO

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About This Item

Linear Formula:
Li6.24La3Zr2Al0.24O11.98
UNSPSC Code:
12352303
NACRES:
NA.23

grade

battery grade

Quality Level

assay

≥99.5%

form

powder

mol wt

Mw 840.62 g/mol

composition

Li6.24La3Zr2Al0.24O11.98

surface area

0.50 m2/g

particle size

5-6 μm (average)

conductivity

0.01-0.1 mS/cm (Ionic conductivity, unsintered, cold-pressed pellet at RT)

density

5.093 g/cm3 (lit.)

application(s)

battery manufacturing

General description

Battery-grade Al-doped Lithium Lanthanum Zirconate Oxide (LLZO) powder is a high-purity, inorganic material that is specifically designed for use in advanced battery applications. It is a white, crystalline powder with an average particle size of 5-6 microns and is composed of lithium, lanthanum, zirconium, oxygen, and a small amount of aluminum dopant. This material is known for its high ionic conductivity, which falls within the range of 0.01-0.1 mS/cm, making it an ideal electrolyte material for use in solid-state lithium-ion batteries. Moreover, the high purity and narrow particle size distribution of this powder make it well-suited for use in the precise and reproducible manufacturing of battery components.

Application

The primary application of Al-doped LLZO powder is in all-solid-state and hybrid electrolytes for lithium-ion batteries. The unique combination of properties, including its high lithium-ion conductivity, robust chemical stability, and wide electrochemical stability window, make it a promising candidate for the next generation of solid-state batteries. This material has the potential to replace the conventional liquid electrolyte in lithium-ion batteries, offering higher energy density, improved safety, and longer lifespan.

Features and Benefits

Our LLZO powder provides high ionic conductivity and consistent particle size for reproducible results.
  • Improved Battery Safety
  • Increased Energy Density

pictograms

CorrosionExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

target_organs

Respiratory system

Storage Class

8A - Combustible corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Lithium battery chemistries enabled by solid-state electrolytes
Manthiram A, et al.
Nature Reviews. Materials, 16103-16103 (2017)
Mechanosynthesis of Solid Electrolytes: Preparation, Characterization, and Li Ion Transport Properties of Garnet-Type Al-Doped Li7La3Zr2O12 Crystallizing with Cubic Symmetry
Duvel A, et al.
The Journal of Physical Chemistry C, 116(29), 15192-15202 (2012)

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