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918008

GPhos

greener alternative

≥95%, powder

Synonym(s):

(3-(tert-Butoxy)-2′,6′-diisopropyl-6-methoxy-[1,1′-biphenyl]-2-yl)dicyclohexylphosphane

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Pack SizeSKUAvailabilityPrice
50 mg

Available to ship TODAYfromMILWAUKEE

$204.00
250 mg

Available to ship TODAYfromMILWAUKEE

$681.00

About This Item

Empirical Formula (Hill Notation):
C35H53O2P
CAS Number:
Molecular Weight:
536.77
UNSPSC Code:
12352128
NACRES:
NA.22

$204.00


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Product Name

GPhos, ≥95%

Quality Level

product line

Buchwald Ligand

assay

≥95%

form

powder

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings, reagent type: ligand

greener alternative product score

old score: 16
new score: 13
Find out more about DOZN™ Scoring

greener alternative product characteristics

Designing Safer Chemicals
Safer Solvents and Auxiliaries
Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

230-233 °C

functional group

phosphine

greener alternative category

General description

We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives . This product belongs to category of Re-engineered products, showing key improvements in Green Chemistry Principles “Designing Safer Chemicals”, “Safer Solvents and Auxiliaries” and “Design for Energy Efficiency”. Click here to view its DOZN scorecard.

Application

GPhos is a dialkylbiaryl monophosphine ligand developed by the Buchwald group for aryl amination reactions. The GPhos Pd oxidative addition complex (OAC) enables room temperature C-N couplings with complex substrates at higher efficiency than previously developed ligands.

Learn more about Buchwald Phosphine Ligands

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718742918989928348
sustainability

Greener Alternative Product

sustainability

Greener Alternative Product

sustainability

-

sustainability

-

Quality Level

100

Quality Level

300

Quality Level

100

Quality Level

100

greener alternative product characteristics

Designing Safer Chemicals
Safer Solvents and Auxiliaries
Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

Waste Prevention
Atom Economy
Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

greener alternative product characteristics

-

greener alternative product characteristics

-

mp

230-233 °C

mp

187-195 °C

mp

-

mp

-

greener alternative category

Re-engineered

greener alternative category

, Re-engineered

greener alternative category

-

greener alternative category

-

assay

≥95%

assay

98%

assay

≥95%

assay

-


Storage Class

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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Global Trade Item Number

SKUGTIN
918008-250MG04061841605966
918008-50MG04061841605973

Questions

1–2 of 2 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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